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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F12%3A43893489%21RIV13-GA0-22310___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
A commercially available hydroxyl terminated low molecular cis-1,4-polybutadiene was modified by carboxylic functions and used as an effective support in single-site alpha-olefin polymerization. Dynamic light scattering analysis of support solution in heptane confirmed increased ability to self-assembly of modified polybutadienes in the presence of methylaluminoxane cocatalyst (MAO). alpha-Diimine nickel and bis(indenyl) zirconium dichloride catalysts activated by trimethylaluminium or MAO cocatalysts were encapsulated into polymer micellar aggregates and used for ethylene and octadec-1-ene polymerization. Furthermore, the effects of cocatalyst type and concentration on the micelle-formation process, activity and morphology of polyethylene (polyoctadec-1-ene) particles were investigated. In the presence of polybutadiene supports, formation of spherical micrometric PE beads was observed during MAO cocatalyzed ethylene polymerization, whereas the activity of polymerization was not decreased. A commercially available hydroxyl terminated low molecular cis-1,4-polybutadiene was modified by carboxylic functions and used as an effective support in single-site alpha-olefin polymerization. Dynamic light scattering analysis of support solution in heptane confirmed increased ability to self-assembly of modified polybutadienes in the presence of methylaluminoxane cocatalyst (MAO). alpha-Diimine nickel and bis(indenyl) zirconium dichloride catalysts activated by trimethylaluminium or MAO cocatalysts were encapsulated into polymer micellar aggregates and used for ethylene and octadec-1-ene polymerization. Furthermore, the effects of cocatalyst type and concentration on the micelle-formation process, activity and morphology of polyethylene (polyoctadec-1-ene) particles were investigated. In the presence of polybutadiene supports, formation of spherical micrometric PE beads was observed during MAO cocatalyzed ethylene polymerization, whereas the activity of polymerization was not decreased.
dcterms:title
Control of morphology in olefin polymerization catalyzed by nickel diimine complexes encapsulated into polybutadiene based support Control of morphology in olefin polymerization catalyzed by nickel diimine complexes encapsulated into polybutadiene based support
skos:prefLabel
Control of morphology in olefin polymerization catalyzed by nickel diimine complexes encapsulated into polybutadiene based support Control of morphology in olefin polymerization catalyzed by nickel diimine complexes encapsulated into polybutadiene based support
skos:notation
RIV/60461373:22310/12:43893489!RIV13-GA0-22310___
n19:predkladatel
n20:orjk%3A22310
n3:aktivita
n10:P n10:Z
n3:aktivity
P(GP104/07/P264), Z(MSM6046137302)
n3:cisloPeriodika
3
n3:dodaniDat
n12:2013
n3:domaciTvurceVysledku
n5:3821013 n5:7236824
n3:druhVysledku
n21:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
128692
n3:idVysledku
RIV/60461373:22310/12:43893489
n3:jazykVysledku
n13:eng
n3:klicovaSlova
nickel diimine catalyst, morphology, olefin polymerization, polybutadiene support
n3:klicoveSlovo
n8:polybutadiene%20support n8:morphology n8:nickel%20diimine%20catalyst n8:olefin%20polymerization
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[2E67432E94FA]
n3:nazevZdroje
POLYMER CHEMISTRY
n3:obor
n15:CD
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
4
n3:projekt
n11:GP104%2F07%2FP264
n3:rokUplatneniVysledku
n12:2012
n3:svazekPeriodika
3
n3:tvurceVysledku
Cramail, Henri Heurtefeu, Bertrand Hošťálek, Zdeněk Merna, Jan
n3:wos
000300049900015
n3:zamer
n9:MSM6046137302
s:issn
1759-9954
s:numberOfPages
10
n17:doi
10.1039/C2py00482h
n7:organizacniJednotka
22310