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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F10%3A00023619%21RIV11-GA0-22310___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
For the first time, domains with twisted structures have been established in planar samples of achiral compounds in tilted smectic C phase. This evidences separation of molecular conformers differring in axial chirality and confirms polar C2 symmetry of these domains. A simple model considering polar surface anchoring energy and bulk energy of the twist can account for this finding. Conditions for coexistence of twisted and homogeneous domains are discussed. For the first time, domains with twisted structures have been established in planar samples of achiral compounds in tilted smectic C phase. This evidences separation of molecular conformers differring in axial chirality and confirms polar C2 symmetry of these domains. A simple model considering polar surface anchoring energy and bulk energy of the twist can account for this finding. Conditions for coexistence of twisted and homogeneous domains are discussed.
dcterms:title
Experimental proof of symmetry breaking in tilted smectics composed of achiral molecules. Experimental proof of symmetry breaking in tilted smectics composed of achiral molecules.
skos:prefLabel
Experimental proof of symmetry breaking in tilted smectics composed of achiral molecules. Experimental proof of symmetry breaking in tilted smectics composed of achiral molecules.
skos:notation
RIV/60461373:22310/10:00023619!RIV11-GA0-22310___
n3:aktivita
n15:Z n15:P
n3:aktivity
P(GA202/09/0047), P(IAA100100911), P(OC10006), Z(AV0Z10100520), Z(MSM6046137301)
n3:cisloPeriodika
22
n3:dodaniDat
n5:2011
n3:domaciTvurceVysledku
n12:8108064 n12:1270095 n12:9184120
n3:druhVysledku
n19:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
258325
n3:idVysledku
RIV/60461373:22310/10:00023619
n3:jazykVysledku
n7:eng
n3:klicovaSlova
liquid crystals; atropoisomeric; axial chirality
n3:klicoveSlovo
n13:atropoisomeric n13:axial%20chirality n13:liquid%20crystals
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[4A287209F371]
n3:nazevZdroje
Journal of Chemical Physics
n3:obor
n4:JJ
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
6
n3:projekt
n6:IAA100100911 n6:GA202%2F09%2F0047 n6:OC10006
n3:rokUplatneniVysledku
n5:2010
n3:svazekPeriodika
133
n3:tvurceVysledku
Hampl, František Svoboda, Jiří Novotná, Vladimíra Glogarová, Milada Lejček, Lubor Cigl, Martin
n3:wos
000285477800002
n3:zamer
n11:MSM6046137301 n11:AV0Z10100520
s:issn
0021-9606
s:numberOfPages
4
n18:organizacniJednotka
22310