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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F10%3A00023040%21RIV11-MSM-22310___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Abstract Homogeneous catalysts, which are mixed with the reactants at the molecular level, typically show the highest activity and selectivity as they offer chemically well-defined active sites and are not limited by heat and mass transport. However, an inherent disadvantage of the homogeneous catalysis is the need to separate the catalyst from a product after the reaction. Therefore, solid or immobilized homogeneous catalysts are preferred in industry. In this contribution we pay attention to chemoselectivity, regioselectivity and enantio?selectivity in the synthesis of fine chemicals by means of hydrogenation reactions with immobilised homogeneous complexes. Preferential hydrogenation of one functional group in a molecule over another is the chemoselective process, while regioselective hydrogenation is the prefe-rential formation of one constitutional isomer of the product in a reaction in which other isomers may also be formed, and the stereoselective hydrogenation is the formation of an excess of Abstract Homogeneous catalysts, which are mixed with the reactants at the molecular level, typically show the highest activity and selectivity as they offer chemically well-defined active sites and are not limited by heat and mass transport. However, an inherent disadvantage of the homogeneous catalysis is the need to separate the catalyst from a product after the reaction. Therefore, solid or immobilized homogeneous catalysts are preferred in industry. In this contribution we pay attention to chemoselectivity, regioselectivity and enantio?selectivity in the synthesis of fine chemicals by means of hydrogenation reactions with immobilised homogeneous complexes. Preferential hydrogenation of one functional group in a molecule over another is the chemoselective process, while regioselective hydrogenation is the prefe-rential formation of one constitutional isomer of the product in a reaction in which other isomers may also be formed, and the stereoselective hydrogenation is the formation of an excess of
dcterms:title
Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production
skos:prefLabel
Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes, in Heterogenized Homogeneous Catalysts for Fine Chemicals Production
skos:notation
RIV/60461373:22310/10:00023040!RIV11-MSM-22310___
n4:aktivita
n5:Z
n4:aktivity
Z(MSM6046137301)
n4:dodaniDat
n6:2011
n4:domaciTvurceVysledku
n10:1946609 n10:1010034
n4:druhVysledku
n11:C
n4:duvernostUdaju
n19:S
n4:entitaPredkladatele
n15:predkladatel
n4:idSjednocenehoVysledku
250585
n4:idVysledku
RIV/60461373:22310/10:00023040
n4:jazykVysledku
n13:eng
n4:klicovaSlova
Chemoselective Hydrogenation; Enantioselective Hydrogenation; Immobilized Complexes
n4:klicoveSlovo
n14:Enantioselective%20Hydrogenation n14:Chemoselective%20Hydrogenation n14:Immobilized%20Complexes
n4:kontrolniKodProRIV
[E9E66040B4C1]
n4:mistoVydani
Berlin
n4:nazevZdroje
Catalysis by Metal Complexes
n4:obor
n12:CC
n4:pocetDomacichTvurcuVysledku
2
n4:pocetStranKnihy
458
n4:pocetTvurcuVysledku
4
n4:rokUplatneniVysledku
n6:2010
n4:tvurceVysledku
Klusoň, Petr Floriš, Tomáš Notheisz, Ferenz Zsigmond, Agnes
n4:zamer
n20:MSM6046137301
s:numberOfPages
77
n18:hasPublisher
Springer-Verlag
n3:isbn
978-90-481-3695-7
n17:organizacniJednotka
22310