This HTML5 document contains 46 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n13http://localhost/temp/predkladatel/
n7http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n17http://linked.opendata.cz/ontology/domain/vavai/
n14http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F60461373%3A22310%2F08%3A00021359%21RIV10-MSM-22310___/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n6http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n10http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n15http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n12http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n16http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n11http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n5http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F08%3A00021359%21RIV10-MSM-22310___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
This review summarizes literature findings on determination of Pd-particle size and specific surface area of Supported Pd-catalysts. Chemisorption of CO is the most frequent method used for the purpose. The surface density of Pd atoms and chemisorbed CO molecules are the main parameters essential for the exact determination of the area. The generally accepted value - 0.84.10(15) atoms cm(-2) - is the average value for Pd atoms in crystallographic planes (111), (100) and (101). The Surface density of CO Molecules is a crucial parameter for the reaction of CO with Pd, forming several bond types, which leads to different Pd/CO stoichiometries. The paper discusses various factors influencing the stoichiometry, such as the Support type, use of promoters, Pd concentration and its particle size. The Pd-particle size cannot be reliably determined Without using other techniques, such as TEM, FT-IR or temperature programmed desorption of CO. This review summarizes literature findings on determination of Pd-particle size and specific surface area of Supported Pd-catalysts. Chemisorption of CO is the most frequent method used for the purpose. The surface density of Pd atoms and chemisorbed CO molecules are the main parameters essential for the exact determination of the area. The generally accepted value - 0.84.10(15) atoms cm(-2) - is the average value for Pd atoms in crystallographic planes (111), (100) and (101). The Surface density of CO Molecules is a crucial parameter for the reaction of CO with Pd, forming several bond types, which leads to different Pd/CO stoichiometries. The paper discusses various factors influencing the stoichiometry, such as the Support type, use of promoters, Pd concentration and its particle size. The Pd-particle size cannot be reliably determined Without using other techniques, such as TEM, FT-IR or temperature programmed desorption of CO.
dcterms:title
Carbon Monoxide Chemisorption on Palladium Surface Carbon Monoxide Chemisorption on Palladium Surface
skos:prefLabel
Carbon Monoxide Chemisorption on Palladium Surface Carbon Monoxide Chemisorption on Palladium Surface
skos:notation
RIV/60461373:22310/08:00021359!RIV10-MSM-22310___
n3:aktivita
n12:S
n3:aktivity
S
n3:cisloPeriodika
12
n3:dodaniDat
n5:2010
n3:domaciTvurceVysledku
n7:2775255 n7:4568621
n3:druhVysledku
n11:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
358823
n3:idVysledku
RIV/60461373:22310/08:00021359
n3:jazykVysledku
n15:eng
n3:klicovaSlova
METAL-SUPPORT INTERACTION; CONTROLLED COLLOIDAL SYNTHESIS; PARTICLE-SIZE; PD CATALYSTS; CO ADSORPTION; SELECTIVE HYDROGENATION; METHANOL SYNTHESIS; PD/SIO2 CATALYSTS; SILICA; SMSI
n3:klicoveSlovo
n6:SILICA n6:METAL-SUPPORT%20INTERACTION n6:METHANOL%20SYNTHESIS n6:PD%20CATALYSTS n6:PD%2FSIO2%20CATALYSTS n6:PARTICLE-SIZE n6:CO%20ADSORPTION n6:CONTROLLED%20COLLOIDAL%20SYNTHESIS n6:SELECTIVE%20HYDROGENATION n6:SMSI
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[9DADF14879F9]
n3:nazevZdroje
Chemické listy
n3:obor
n16:CA
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:rokUplatneniVysledku
n5:2008
n3:svazekPeriodika
102
n3:tvurceVysledku
Dvořák, Bohumír Dudková, Iva
n3:wos
000262061500003
s:issn
0009-2770
s:numberOfPages
7
n13:organizacniJednotka
22310