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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F08%3A00020047%21RIV09-MSM-22310___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
9-Benzyl-6-iodopurine affords under the conditions of the Heck reaction mainly the corresponding 6,6´-dimer. The Heck product is formed in low yield (<= 12%). With 7-benzyl-6-iodopurine the dimerization is suppressed and the Heck product is obtained in 32 - 91% yield. 9-Substituted 6-chloro-2-iodopurines react smoothly giving 2-alkenyl-6-chloropurines in 71 - 97 % isolated yield. 9-Benzyl-6-iodopurine affords under the conditions of the Heck reaction mainly the corresponding 6,6´-dimer. The Heck product is formed in low yield (<= 12%). With 7-benzyl-6-iodopurine the dimerization is suppressed and the Heck product is obtained in 32 - 91% yield. 9-Substituted 6-chloro-2-iodopurines react smoothly giving 2-alkenyl-6-chloropurines in 71 - 97 % isolated yield. 9-Benzyl-6-iodopuriny poskytuje za podmínek Heckovy reakce převážně odpovídající 6,6´-dimer.
dcterms:title
Heck Reactions of 6- and 2-Halopurines Heckova reakce 6- a 2-halogenpurinů Heck Reactions of 6- and 2-Halopurines
skos:prefLabel
Heckova reakce 6- a 2-halogenpurinů Heck Reactions of 6- and 2-Halopurines Heck Reactions of 6- and 2-Halopurines
skos:notation
RIV/60461373:22310/08:00020047!RIV09-MSM-22310___
n4:aktivita
n11:P n11:Z
n4:aktivity
P(GA203/06/0888), P(LC06070), Z(MSM6046137301)
n4:cisloPeriodika
17
n4:dodaniDat
n9:2009
n4:domaciTvurceVysledku
n12:5078008 n12:6702198
n4:druhVysledku
n5:J
n4:duvernostUdaju
n13:S
n4:entitaPredkladatele
n17:predkladatel
n4:idSjednocenehoVysledku
369914
n4:idVysledku
RIV/60461373:22310/08:00020047
n4:jazykVysledku
n6:eng
n4:klicovaSlova
Nucleobases; Homogeneous catalysis; Nitrogen heterocycles; Heck reaction
n4:klicoveSlovo
n14:Nucleobases n14:Heck%20reaction n14:Nitrogen%20heterocycles n14:Homogeneous%20catalysis
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[22AA32509D7D]
n4:nazevZdroje
European Journal of Organic Chemistry
n4:obor
n15:CC
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
2
n4:projekt
n10:GA203%2F06%2F0888 n10:LC06070
n4:rokUplatneniVysledku
n9:2008
n4:tvurceVysledku
Tobrman, Tomáš Dvořák, Dalimil
n4:wos
000257045000008
n4:zamer
n16:MSM6046137301
s:issn
1434-193X
s:numberOfPages
6
n3:organizacniJednotka
22310