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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F05%3A00015121%21RIV06-MSM-22310___
rdf:type
skos:Concept n14:Vysledek
dcterms:description
The selected pseudobinary, isothermal and isoactivity sections of the Bi2O3-SrO-MnOx phase diagram are constructed from the calculated phase equilibria. The starting point for the thermodynamic analysis were the assessments of the respective ternary systems Bi2O3-SrO, Bi2O3-MnOx and SrO-MnOx. The only quaternary solid phase-the perovskite solid solution-is described in terms of the point defect model [ Bi3+1-xSr2+x] [ Mn3+1-x+2? Mn4+x-2?] [O2-1-?/3 V a?/3]3. The quaternary liquid is approximated by a phenomenological model using the liquid species Mn, MnO, MnO1.5, SrO, and BiO1.5 with only binary Redlich-Kister coefficients. The ab initio electronic structure calculations of cohesive energies are employed to evaluate the enthalpies of formation of some stoichiometric phases. systém Bi-Sr-Mn-O;termodynamické modelování;fázové diagramy The selected pseudobinary, isothermal and isoactivity sections of the Bi2O3-SrO-MnOx phase diagram are constructed from the calculated phase equilibria. The starting point for the thermodynamic analysis were the assessments of the respective ternary systems Bi2O3-SrO, Bi2O3-MnOx and SrO-MnOx. The only quaternary solid phase-the perovskite solid solution-is described in terms of the point defect model [ Bi3+1-xSr2+x] [ Mn3+1-x+2? Mn4+x-2?] [O2-1-?/3 V a?/3]3. The quaternary liquid is approximated by a phenomenological model using the liquid species Mn, MnO, MnO1.5, SrO, and BiO1.5 with only binary Redlich-Kister coefficients. The ab initio electronic structure calculations of cohesive energies are employed to evaluate the enthalpies of formation of some stoichiometric phases.
dcterms:title
Phase equilibria modelling in Bi-Sr-Mn-O system Phase equilibria modelling in Bi-Sr-Mn-O system Modelování fázových rovnovah v systému Bi-Sr-Mn-O
skos:prefLabel
Phase equilibria modelling in Bi-Sr-Mn-O system Phase equilibria modelling in Bi-Sr-Mn-O system Modelování fázových rovnovah v systému Bi-Sr-Mn-O
skos:notation
RIV/60461373:22310/05:00015121!RIV06-MSM-22310___
n3:aktivita
n17:Z
n3:aktivity
Z(MSM 223100002)
n3:dodaniDat
n12:2006
n3:domaciTvurceVysledku
n11:6541690 n11:1355686 n11:5395097 n11:5094763
n3:druhVysledku
n15:O
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n4:predkladatel
n3:idSjednocenehoVysledku
535868
n3:idVysledku
RIV/60461373:22310/05:00015121
n3:jazykVysledku
n10:eng
n3:klicovaSlova
Phase equilibria modelling in Bi-Sr-Mn-O system
n3:klicoveSlovo
n7:Phase%20equilibria%20modelling%20in%20Bi-Sr-Mn-O%20system
n3:kontrolniKodProRIV
[2914AAF472A5]
n3:obor
n9:JH
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n12:2005
n3:tvurceVysledku
Nevřiva, Miloš Leitner, Jindřich Strejc, Aleš Beneš, Ondřej Sedmidubský, David
n3:zamer
n5:MSM%20223100002
n13:organizacniJednotka
22310