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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F04%3A00011562%21RIV%2F2005%2FMSM%2F223105%2FN
rdf:type
n3:Vysledek skos:Concept
dcterms:description
Ferrate (VI) production by electrochemical oxidation of iron anodes that differ in their carbon content was studied in a batch?operating mode. White cast iron was identified as the most suitable anode material. This was explained in terms of deteriorated passivating properties of an oxy-hydroxide layer covering the surface of this anode material. This explanation was supported by the results of the electrochemical impedance study over a wide range of passive and transpassive potentials performed using electrodes made of pure and white cast iron. At the same time, it has been found that the anode material influences the stability of ferrate (VI) produced. In order to understand in more detail the properties of the oxy-hydroxide layer passivating the anode surface, an in situ Mössbauer spectroscopy study in the transpassive potential region was performed at different electrolyte concentrations (0.1 ? 14 M NaOH). The layer was found to consist of two sublayers differing in their protective properties aga Vliv materiálu anody na elektrochemickou přípravu železanu Ferrate (VI) production by electrochemical oxidation of iron anodes that differ in their carbon content was studied in a batch?operating mode. White cast iron was identified as the most suitable anode material. This was explained in terms of deteriorated passivating properties of an oxy-hydroxide layer covering the surface of this anode material. This explanation was supported by the results of the electrochemical impedance study over a wide range of passive and transpassive potentials performed using electrodes made of pure and white cast iron. At the same time, it has been found that the anode material influences the stability of ferrate (VI) produced. In order to understand in more detail the properties of the oxy-hydroxide layer passivating the anode surface, an in situ Mössbauer spectroscopy study in the transpassive potential region was performed at different electrolyte concentrations (0.1 ? 14 M NaOH). The layer was found to consist of two sublayers differing in their protective properties aga
dcterms:title
Vliv materiálu anody na elektrochemickou přípravu železanu Anode Material Aspects of the Electrochemical Ferrate (VI) Synthesis Anode Material Aspects of the Electrochemical Ferrate (VI) Synthesis
skos:prefLabel
Anode Material Aspects of the Electrochemical Ferrate (VI) Synthesis Anode Material Aspects of the Electrochemical Ferrate (VI) Synthesis Vliv materiálu anody na elektrochemickou přípravu železanu
skos:notation
RIV/60461373:22310/04:00011562!RIV/2005/MSM/223105/N
n4:strany
9-19
n4:aktivita
n20:Z
n4:aktivity
Z(MSM 223100001)
n4:dodaniDat
n17:2005
n4:domaciTvurceVysledku
n5:2059428 n5:6286631
n4:druhVysledku
n14:D
n4:duvernostUdaju
n19:S
n4:entitaPredkladatele
n7:predkladatel
n4:idSjednocenehoVysledku
554724
n4:idVysledku
RIV/60461373:22310/04:00011562
n4:jazykVysledku
n9:eng
n4:klicovaSlova
ferrate;anode material;electrochemical impendance spectroscopy;Mössbauer spectroscopy
n4:klicoveSlovo
n10:anode%20material n10:M%C3%B6ssbauer%20spectroscopy n10:ferrate n10:electrochemical%20impendance%20spectroscopy
n4:kontrolniKodProRIV
[E9DBD5AC3DED]
n4:mistoKonaniAkce
Praha
n4:mistoVydani
Praha
n4:nazevZdroje
Proceedings of the International Symposium : Innovative Ferrate (VI) Technology in Water and Wastewater Treatment
n4:obor
n12:CG
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
2
n4:rokUplatneniVysledku
n17:2004
n4:tvurceVysledku
Bouzek, Karel Mácová, Zuzana
n4:typAkce
n21:WRD
n4:zahajeniAkce
2004-05-31+02:00
n4:zamer
n15:MSM%20223100001
s:numberOfPages
10
n6:hasPublisher
Vysoká škola chemicko-technologická v Praze
n13:isbn
80-7080-540-4
n16:organizacniJednotka
22310