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Statements

Subject Item
n2:RIV%2F60461373%3A22310%2F01%3A00003979%21RIV%2F2004%2FMSM%2F223104%2FN
rdf:type
n9:Vysledek skos:Concept
dcterms:description
Electroreductions of Ni2+, Cu2+ and Zn2+ complexes of azinyl (pyridin-2-yl, pyridazin-3-yl, pyrimidin-2-yl, pyrimidin-4-yl, pyrazinyl) methyl ketoximes on mercury electrode were studied using dc polarography. Three different types of complex behaviour onthe mercury electrode were observed: In the Ni2+ complexes, the hydroxyimino group of the ligand is reduced, whereas in the Cu2+ complexes, the reduction proceeds on the metal ion. With Zn2+complex of methyl pyridin-2-yl ketoxime, only reduction waves o f the uncoordinated ligand and metal were observed due to a rapid decomplexation pre-equilibrium. Electroreductions of Ni2+, Cu2+ and Zn2+ complexes of azinyl (pyridin-2-yl, pyridazin-3-yl, pyrimidin-2-yl, pyrimidin-4-yl, pyrazinyl) methyl ketoximes on mercury electrode were studied using dc polarography. Three different types of complex behaviour onthe mercury electrode were observed: In the Ni2+ complexes, the hydroxyimino group of the ligand is reduced, whereas in the Cu2+ complexes, the reduction proceeds on the metal ion. With Zn2+complex of methyl pyridin-2-yl ketoxime, only reduction waves o f the uncoordinated ligand and metal were observed due to a rapid decomplexation pre-equilibrium.
dcterms:title
Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury
skos:prefLabel
Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury Electrochemical Reductions of Ni2+, Cu2+ and Zn2+ Complexes of Azinyl Methyl Ketoximes on Mercury
skos:notation
RIV/60461373:22310/01:00003979!RIV/2004/MSM/223104/N
n3:strany
170-184
n3:aktivita
n12:P n12:Z
n3:aktivity
P(GA203/97/0805), P(GA203/99/M037), Z(AV0Z4040901), Z(AV0Z5052915), Z(MSM 113100001), Z(MSM 223100001)
n3:cisloPeriodika
1
n3:dodaniDat
n13:2004
n3:domaciTvurceVysledku
n4:5612640 n4:6624707
n3:druhVysledku
n15:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
679106
n3:idVysledku
RIV/60461373:22310/01:00003979
n3:jazykVysledku
n8:eng
n3:klicovaSlova
Complexes, Electrochemistry, Oximes, Polarography, Reductions, Crystal structure determination
n3:klicoveSlovo
n5:Complexes n5:Reductions n5:Crystal%20structure%20determination n5:Oximes n5:Electrochemistry n5:Polarography
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[6DBEAFD17967]
n3:nazevZdroje
Collection of Czechoslovak Chemical Communications
n3:obor
n7:CC
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
5
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n18:GA203%2F97%2F0805 n18:GA203%2F99%2FM037
n3:rokUplatneniVysledku
n13:2001
n3:svazekPeriodika
66
n3:tvurceVysledku
Ondráček, Jan Cibulka, Radek Císařová, Ivana Ludvík, Jiří Liška, František
n3:zamer
n11:AV0Z4040901 n11:MSM%20223100001 n11:MSM%20113100001 n11:AV0Z5052915
s:issn
0010-0765
s:numberOfPages
15
n10:organizacniJednotka
22310