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Statements

Subject Item
n2:RIV%2F60460709%3A41330%2F13%3A63629%21RIV14-MSM-41330___
rdf:type
n6:Vysledek skos:Concept
dcterms:description
From extraction experiments and.-activity measurements, the exchange extraction constant corresponding to the equilibrium Zn2+(aq) + 1 center dot Sr2+(nb) double left right arrow 1 center dot Zn2+(nb) + Sr2+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K-ex (Zn2+, 1 center dot Sr2+) = -0.3 +/- 0.1. Further, the stability constant of the beauvericin - zinc complex (abbrev. 1 center dot Zn2+) in nitrobenzene saturated with water was calculated for a temperature of 25 degrees C: log beta(nb) (1 center dot Zn2+) = 9.1 +/- 0.2. Finally, by using quantum mechanical DFT calculations, the most probable structure of the 1 center dot Zn2+ complex species was predicted. From extraction experiments and.-activity measurements, the exchange extraction constant corresponding to the equilibrium Zn2+(aq) + 1 center dot Sr2+(nb) double left right arrow 1 center dot Zn2+(nb) + Sr2+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K-ex (Zn2+, 1 center dot Sr2+) = -0.3 +/- 0.1. Further, the stability constant of the beauvericin - zinc complex (abbrev. 1 center dot Zn2+) in nitrobenzene saturated with water was calculated for a temperature of 25 degrees C: log beta(nb) (1 center dot Zn2+) = 9.1 +/- 0.2. Finally, by using quantum mechanical DFT calculations, the most probable structure of the 1 center dot Zn2+ complex species was predicted.
dcterms:title
Extraction and DFT Study on the Complexation of Zn2+ with Beauvericin Extraction and DFT Study on the Complexation of Zn2+ with Beauvericin
skos:prefLabel
Extraction and DFT Study on the Complexation of Zn2+ with Beauvericin Extraction and DFT Study on the Complexation of Zn2+ with Beauvericin
skos:notation
RIV/60460709:41330/13:63629!RIV14-MSM-41330___
n6:predkladatel
n11:orjk%3A41330
n3:aktivita
n12:S
n3:aktivity
S
n3:cisloPeriodika
4
n3:dodaniDat
n5:2014
n3:domaciTvurceVysledku
n15:9843167
n3:druhVysledku
n13:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
74430
n3:idVysledku
RIV/60460709:41330/13:63629
n3:jazykVysledku
n10:eng
n3:klicovaSlova
Beauvericin, zinc cation, complexation, extraction and stability constants, water – nitrobenzene system, DFT, complex structure
n3:klicoveSlovo
n4:complex%20structure n4:water%20%E2%80%93%20nitrobenzene%20system n4:complexation n4:Beauvericin n4:zinc%20cation n4:DFT n4:extraction%20and%20stability%20constants
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[1D613D065410]
n3:nazevZdroje
ACTA CHIMICA SLOVENICA
n3:obor
n14:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n5:2013
n3:svazekPeriodika
60
n3:tvurceVysledku
Toman, Petr Makrlík, Emanuel Vaňura, Petr
n3:wos
000329194200021
s:issn
1318-0207
s:numberOfPages
5
n18:organizacniJednotka
41330