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Statements

Subject Item
n2:RIV%2F60460709%3A41330%2F13%3A63627%21RIV14-MSM-41330___
rdf:type
n9:Vysledek skos:Concept
dcterms:description
From extraction experiments and gamma-activity measurements, the exchange extraction constant corresponding to the equilibrium Ca2+(aq) + 1 center dot Sr2+(nb) a double dagger%22 1 center dot Ca2+(nb) + Sr2+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K (ex)(Ca2+, 1 center dot Sr2+) = 1.1 +/- A 0.1. Further, the stability constant of the 1 center dot Ca2+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 A degrees C: log beta (nb)(1 center dot Ca2+) = 10.1 +/- A 0.2. Finally, by using quantum mechanical density functional level of theory calculations, the most probable structures of the non-hydrated 1 center dot Ca2+ and hydrated 1 center dot Ca2+center dot H2O complex species were predicted. From extraction experiments and gamma-activity measurements, the exchange extraction constant corresponding to the equilibrium Ca2+(aq) + 1 center dot Sr2+(nb) a double dagger%22 1 center dot Ca2+(nb) + Sr2+(aq) taking place in the two-phase water-nitrobenzene system (1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K (ex)(Ca2+, 1 center dot Sr2+) = 1.1 +/- A 0.1. Further, the stability constant of the 1 center dot Ca2+ complex in nitrobenzene saturated with water was calculated for a temperature of 25 A degrees C: log beta (nb)(1 center dot Ca2+) = 10.1 +/- A 0.2. Finally, by using quantum mechanical density functional level of theory calculations, the most probable structures of the non-hydrated 1 center dot Ca2+ and hydrated 1 center dot Ca2+center dot H2O complex species were predicted.
dcterms:title
Experimental and theoretical study on the complexation of Ca2+ with beauvericin Experimental and theoretical study on the complexation of Ca2+ with beauvericin
skos:prefLabel
Experimental and theoretical study on the complexation of Ca2+ with beauvericin Experimental and theoretical study on the complexation of Ca2+ with beauvericin
skos:notation
RIV/60460709:41330/13:63627!RIV14-MSM-41330___
n9:predkladatel
n10:orjk%3A41330
n4:aktivita
n13:S
n4:aktivity
S
n4:cisloPeriodika
1
n4:dodaniDat
n6:2014
n4:domaciTvurceVysledku
n17:9843167
n4:druhVysledku
n11:J
n4:duvernostUdaju
n14:S
n4:entitaPredkladatele
n16:predkladatel
n4:idSjednocenehoVysledku
74014
n4:idVysledku
RIV/60460709:41330/13:63627
n4:jazykVysledku
n12:eng
n4:klicovaSlova
Calcium, Beauvericin, Complexation, Water–nitrobenzene system, Extraction and stability constants, DFT calculations, Structures.
n4:klicoveSlovo
n5:Water%E2%80%93nitrobenzene%20system n5:Complexation n5:Calcium n5:Beauvericin n5:Structures. n5:DFT%20calculations n5:Extraction%20and%20stability%20constants
n4:kodStatuVydavatele
HU - Maďarsko
n4:kontrolniKodProRIV
[34961EE59BD8]
n4:nazevZdroje
Journal of Radioanalytical and Nuclear Chemistry
n4:obor
n15:CF
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
3
n4:rokUplatneniVysledku
n6:2013
n4:svazekPeriodika
298
n4:tvurceVysledku
Makrlík, Emanuel Toman, Petr Vaňura, Petr
n4:wos
000324546100025
s:issn
0236-5731
s:numberOfPages
6
n18:organizacniJednotka
41330