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Statements

Subject Item
n2:RIV%2F60460709%3A41330%2F13%3A61047%21RIV14-MSM-41330___
rdf:type
n8:Vysledek skos:Concept
dcterms:description
Solvent extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of dodecaethylene glycol (DDEG, L) has been investigated. The equilibrium data have been explained assuming that the species HL+, H2L2+, ML2+ and MHL3+ (M2+ = Ca2+, Sr2+; L = DDEG) are extracted into the organic phase. The values of extraction and stability constants of the complex species in nitrobenzene saturated with water have been determined. It was found that in this nitrobenzene medium, the stability constant of the SrL2+ complex is somewhat higher than that of CaL2+. Solvent extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of dodecaethylene glycol (DDEG, L) has been investigated. The equilibrium data have been explained assuming that the species HL+, H2L2+, ML2+ and MHL3+ (M2+ = Ca2+, Sr2+; L = DDEG) are extracted into the organic phase. The values of extraction and stability constants of the complex species in nitrobenzene saturated with water have been determined. It was found that in this nitrobenzene medium, the stability constant of the SrL2+ complex is somewhat higher than that of CaL2+.
dcterms:title
Synergistic extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol Synergistic extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol
skos:prefLabel
Synergistic extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol Synergistic extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol
skos:notation
RIV/60460709:41330/13:61047!RIV14-MSM-41330___
n8:predkladatel
n15:orjk%3A41330
n3:aktivita
n9:S n9:N
n3:aktivity
N, S
n3:cisloPeriodika
3
n3:dodaniDat
n10:2014
n3:domaciTvurceVysledku
n14:9843167
n3:druhVysledku
n6:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
109417
n3:idVysledku
RIV/60460709:41330/13:61047
n3:jazykVysledku
n13:eng
n3:klicovaSlova
Calcium, Strontium, Dodecaethylene glycol, Complexation, Water-nitrobenzene system, Extraction and stability constants
n3:klicoveSlovo
n4:Calcium n4:Dodecaethylene%20glycol n4:Strontium n4:Complexation n4:Water-nitrobenzene%20system n4:Extraction%20and%20stability%20constants
n3:kodStatuVydavatele
HU - Maďarsko
n3:kontrolniKodProRIV
[1316B0E41DA5]
n3:nazevZdroje
Journal of Radioanalytical and Nuclear Chemistry
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n10:2013
n3:svazekPeriodika
295
n3:tvurceVysledku
Vaňura, Petr Makrlík, Emanuel Selucký, P.
n3:wos
000314895400081
s:issn
0236-5731
s:numberOfPages
6
n16:organizacniJednotka
41330