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Statements

Subject Item
n2:RIV%2F60460709%3A41330%2F13%3A61001%21RIV14-MSM-41330___
rdf:type
skos:Concept n13:Vysledek
dcterms:description
Benzoate anion forms a strong complex with meso-octamethylcalix[4]pyrrole in nitrobenzene with the stabilization constant K = 3.88 x 10(5) mol(-1) L-1 at 298 K. According to NMR and FTIR spectra and DFT calculations, the benzoate anion is symmetrically bound by two pairs of hydrogen bonds to its oxygen atoms. The bound anion is prone to fast exchange with a free anion of the same kind, the exchange correlation time being 4.93 x 10(-5) s at 298 K. (C) 2013 Elsevier B. V. All rights reserved. Benzoate anion forms a strong complex with meso-octamethylcalix[4]pyrrole in nitrobenzene with the stabilization constant K = 3.88 x 10(5) mol(-1) L-1 at 298 K. According to NMR and FTIR spectra and DFT calculations, the benzoate anion is symmetrically bound by two pairs of hydrogen bonds to its oxygen atoms. The bound anion is prone to fast exchange with a free anion of the same kind, the exchange correlation time being 4.93 x 10(-5) s at 298 K. (C) 2013 Elsevier B. V. All rights reserved.
dcterms:title
NMR, FTIR and DFT study of the interaction of the benzoate anion with meso-octamethylcalix[4]pyrrole NMR, FTIR and DFT study of the interaction of the benzoate anion with meso-octamethylcalix[4]pyrrole
skos:prefLabel
NMR, FTIR and DFT study of the interaction of the benzoate anion with meso-octamethylcalix[4]pyrrole NMR, FTIR and DFT study of the interaction of the benzoate anion with meso-octamethylcalix[4]pyrrole
skos:notation
RIV/60460709:41330/13:61001!RIV14-MSM-41330___
n13:predkladatel
n14:orjk%3A41330
n3:aktivita
n4:P n4:I n4:Z n4:S
n3:aktivity
I, P(GA203/09/1478), S, Z(AV0Z40500505), Z(AV0Z40550506)
n3:cisloPeriodika
561
n3:dodaniDat
n7:2014
n3:domaciTvurceVysledku
n15:9843167
n3:druhVysledku
n20:J
n3:duvernostUdaju
n19:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
91850
n3:idVysledku
RIV/60460709:41330/13:61001
n3:jazykVysledku
n11:eng
n3:klicovaSlova
ION-PAIR RECEPTOR, EXPANDED PORPHYRIN, CESIUM NITRATE, 1,3-ALTERNATE CONFORMATION, CRYSTAL-STRUCTURES, EXTRACTION, SAPPHYRIN, BINDING, 1,2-DICHLOROETHANE, CALIXCROWNS
n3:klicoveSlovo
n6:1 n6:EXTRACTION n6:SAPPHYRIN n6:CALIXCROWNS n6:CRYSTAL-STRUCTURES n6:3-ALTERNATE%20CONFORMATION n6:2-DICHLOROETHANE n6:EXPANDED%20PORPHYRIN n6:CESIUM%20NITRATE n6:ION-PAIR%20RECEPTOR n6:BINDING
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[9D581E3E4AF6]
n3:nazevZdroje
CHEMICAL PHYSICS LETTERS
n3:obor
n8:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n9:GA203%2F09%2F1478
n3:rokUplatneniVysledku
n7:2013
n3:svazekPeriodika
2013
n3:tvurceVysledku
Sedláková, Zdeňka Kašička, Václav Makrlík, Emanuel Kříž, Jaroslav
n3:wos
000315279600007
n3:zamer
n16:AV0Z40500505 n16:AV0Z40550506
s:issn
0009-2614
s:numberOfPages
4
n17:organizacniJednotka
41330