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Statements

Subject Item
n2:RIV%2F49777513%3A23640%2F14%3A43921829%21RIV15-MSM-23640___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
Pulsed IR laser ablation of ferrous sulfide (FeS) in a vacuum has been studied using scanning and transmission electron microscopy and X-ray diffraction. This allows the analysis of the surface morphology and composition of the irradiated target and also of the coats deposited on unheated Ta, silica and Cu substrates. It is observed that a noncongruent ablation of FeS results in the deposition of nanosized FeS-containing FeS1_x amorphous coats on the silica and tantalum, and in the deposition of crystalline copper sulfide-containing amorphous Cu2S phases on copper. The detected amorphous Cu2S phase, crystalline and nanocrystalline chalcocite Cu2S, bornite Cu5FeS4, digenite Cu9S5 and blaubleibend covellite are formed through the reactive deposition of FeS1_x particles on the topmost Cu layers. This finding is the first example of the reactive deposition of laser ablated inorganic compounds on unheated surfaces and may spur more interest in using this simple process with various inorganic compounds to achieve reactive modifications of other materials. Pulsed IR laser ablation of ferrous sulfide (FeS) in a vacuum has been studied using scanning and transmission electron microscopy and X-ray diffraction. This allows the analysis of the surface morphology and composition of the irradiated target and also of the coats deposited on unheated Ta, silica and Cu substrates. It is observed that a noncongruent ablation of FeS results in the deposition of nanosized FeS-containing FeS1_x amorphous coats on the silica and tantalum, and in the deposition of crystalline copper sulfide-containing amorphous Cu2S phases on copper. The detected amorphous Cu2S phase, crystalline and nanocrystalline chalcocite Cu2S, bornite Cu5FeS4, digenite Cu9S5 and blaubleibend covellite are formed through the reactive deposition of FeS1_x particles on the topmost Cu layers. This finding is the first example of the reactive deposition of laser ablated inorganic compounds on unheated surfaces and may spur more interest in using this simple process with various inorganic compounds to achieve reactive modifications of other materials.
dcterms:title
Reactive deposition of laser ablated FeS1_x particles on a copper surface Reactive deposition of laser ablated FeS1_x particles on a copper surface
skos:prefLabel
Reactive deposition of laser ablated FeS1_x particles on a copper surface Reactive deposition of laser ablated FeS1_x particles on a copper surface
skos:notation
RIV/49777513:23640/14:43921829!RIV15-MSM-23640___
n3:aktivita
n4:P
n3:aktivity
P(ED2.1.00/03.0088)
n3:cisloPeriodika
23
n3:dodaniDat
n14:2015
n3:domaciTvurceVysledku
n9:7012144
n3:druhVysledku
n18:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
41428
n3:idVysledku
RIV/49777513:23640/14:43921829
n3:jazykVysledku
n7:eng
n3:klicovaSlova
inorganic compound; reactive deposition; ablation; Pulsed laser deposition
n3:klicoveSlovo
n8:reactive%20deposition n8:ablation n8:Pulsed%20laser%20deposition n8:inorganic%20compound
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[966F3EA7B7FD]
n3:nazevZdroje
RSC Advances
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
6
n3:projekt
n13:ED2.1.00%2F03.0088
n3:rokUplatneniVysledku
n14:2014
n3:svazekPeriodika
4
n3:tvurceVysledku
Bezdička, Petr Urbanová, Markéta Kupčík, Jaroslav Křenek, Tomáš Pola, Josef Pokorná, Dana
s:issn
2046-2069
s:numberOfPages
9
n5:doi
10.1039/c3ra46580b
n16:organizacniJednotka
23640