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Statements

Subject Item
n2:RIV%2F49777513%3A23640%2F13%3A43920895%21RIV14-MSM-23640___
rdf:type
skos:Concept n6:Vysledek
dcterms:description
At thermal analysis two types of processes are detected: monotropic, where the initial state of the sample unstable and enantiotropic where the initial state is stable but becoming unstable after equilibrium temperature of transition is achieved. The course of enantiotropic processes is therefore limited by so called equilibrium background - temperature dependence of equilibrium states. According to the equilibrium background four types of processes can be distinguished in binary systems, one of which -called gradual transition- is defined by two equilibrium temperatures Tin, Tfin), in which the criteria (proposed by Ehrenfest) for the second kind phase transition are valid. Corresponding Ehrenfest equations are derived for these temperatures At thermal analysis two types of processes are detected: monotropic, where the initial state of the sample unstable and enantiotropic where the initial state is stable but becoming unstable after equilibrium temperature of transition is achieved. The course of enantiotropic processes is therefore limited by so called equilibrium background - temperature dependence of equilibrium states. According to the equilibrium background four types of processes can be distinguished in binary systems, one of which -called gradual transition- is defined by two equilibrium temperatures Tin, Tfin), in which the criteria (proposed by Ehrenfest) for the second kind phase transition are valid. Corresponding Ehrenfest equations are derived for these temperatures
dcterms:title
Equilibrium background of gradual transitions and Ehrenfest equations in binary system Equilibrium background of gradual transitions and Ehrenfest equations in binary system
skos:prefLabel
Equilibrium background of gradual transitions and Ehrenfest equations in binary system Equilibrium background of gradual transitions and Ehrenfest equations in binary system
skos:notation
RIV/49777513:23640/13:43920895!RIV14-MSM-23640___
n6:predkladatel
n7:orjk%3A23640
n3:aktivita
n9:I
n3:aktivity
I
n3:dodaniDat
n8:2014
n3:domaciTvurceVysledku
n17:7582331
n3:druhVysledku
n16:O
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n10:predkladatel
n3:idSjednocenehoVysledku
73145
n3:idVysledku
RIV/49777513:23640/13:43920895
n3:jazykVysledku
n12:eng
n3:klicovaSlova
Ehrenfest equations; Ehrenfest classification; binary system; sharp and gradual phase transition; equilibrium background; enantiotropic and monotropic processes; thermal analysis
n3:klicoveSlovo
n4:sharp%20and%20gradual%20phase%20transition n4:enantiotropic%20and%20monotropic%20processes n4:thermal%20analysis n4:Ehrenfest%20classification n4:Ehrenfest%20equations n4:binary%20system n4:equilibrium%20background
n3:kontrolniKodProRIV
[B9793BA3C669]
n3:obor
n15:BJ
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
1
n3:rokUplatneniVysledku
n8:2013
n3:tvurceVysledku
Holba, Pavel
n5:organizacniJednotka
23640