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Statements

Subject Item
n2:RIV%2F49777513%3A23640%2F13%3A43920747%21RIV14-MSM-23640___
rdf:type
skos:Concept n5:Vysledek
dcterms:description
Historical development of methods and theoretical basis of differential thermal analysis (DTA) are outlined. The measured difference Delta T is not directly proportional to the rate of the process (d alpha/dt) but includes also the effect of heat inertia proportional to the slope d Delta T/dt as it was derived and incorporated into DTA equation by Vold (Anal Chem 21:683-688, 1949), Borchardt and Daniels (J Am Chem Soc 79:41-46, 1957), and suggested to be corrected in the authors' previous papers (1976). DTA experiments with rectangular pulses realized by micro-heater inside the sample show that the correction of DTA signal employing calculated heat inertia term of the DTA equation is reliable but not yet fully sufficient. It was a reason to derive a more complete DTA equation including a term expressing the changes in the temperature field inside the sample during process.. Itemized 150 references with titles. Historical development of methods and theoretical basis of differential thermal analysis (DTA) are outlined. The measured difference Delta T is not directly proportional to the rate of the process (d alpha/dt) but includes also the effect of heat inertia proportional to the slope d Delta T/dt as it was derived and incorporated into DTA equation by Vold (Anal Chem 21:683-688, 1949), Borchardt and Daniels (J Am Chem Soc 79:41-46, 1957), and suggested to be corrected in the authors' previous papers (1976). DTA experiments with rectangular pulses realized by micro-heater inside the sample show that the correction of DTA signal employing calculated heat inertia term of the DTA equation is reliable but not yet fully sufficient. It was a reason to derive a more complete DTA equation including a term expressing the changes in the temperature field inside the sample during process.. Itemized 150 references with titles.
dcterms:title
Heat inertia and temperature gradient in the treatment of DTA peaks. Existing on every occasion of real measurements but until now omitted. Heat inertia and temperature gradient in the treatment of DTA peaks. Existing on every occasion of real measurements but until now omitted.
skos:prefLabel
Heat inertia and temperature gradient in the treatment of DTA peaks. Existing on every occasion of real measurements but until now omitted. Heat inertia and temperature gradient in the treatment of DTA peaks. Existing on every occasion of real measurements but until now omitted.
skos:notation
RIV/49777513:23640/13:43920747!RIV14-MSM-23640___
n5:predkladatel
n6:orjk%3A23640
n3:aktivita
n18:P
n3:aktivity
P(ED2.1.00/03.0088)
n3:cisloPeriodika
3
n3:dodaniDat
n12:2014
n3:domaciTvurceVysledku
n14:4115910 n14:7582331
n3:druhVysledku
n16:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
77158
n3:idVysledku
RIV/49777513:23640/13:43920747
n3:jazykVysledku
n8:eng
n3:klicovaSlova
Non-isothermal kinetics; Quantitative evaluation; Temperature gradient; Peak rectification; Heat inertia effect; Curve distortion; DTA theory; Thermal analysis; History
n3:klicoveSlovo
n4:Temperature%20gradient n4:DTA%20theory n4:Non-isothermal%20kinetics n4:Peak%20rectification n4:Heat%20inertia%20effect n4:Thermal%20analysis n4:History n4:Quantitative%20evaluation n4:Curve%20distortion
n3:kodStatuVydavatele
HU - Maďarsko
n3:kontrolniKodProRIV
[38A7038561B6]
n3:nazevZdroje
Journal of Thermal Analysis and Calorimetry
n3:obor
n11:BJ
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n17:ED2.1.00%2F03.0088
n3:rokUplatneniVysledku
n12:2013
n3:svazekPeriodika
113
n3:tvurceVysledku
Holba, Pavel Šesták, Jaroslav
n3:wos
000323503300080
s:issn
1388-6150
s:numberOfPages
11
n7:doi
10.1007/s10973-013-3025-3
n20:organizacniJednotka
23640