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Statements

Subject Item
n2:RIV%2F46356088%3A_____%2F12%3A%230001252%21RIV13-MPO-46356088
rdf:type
skos:Concept n6:Vysledek
dcterms:description
From extraction experiments and gamma-activity measurements, the exchange extraction constantcorresponding to the general equilibrium Ca2+(aq) + 2HL(nb) double left right arrow CaL2(nb) + 2H(+)(aq) taking place in the two-phase water-nitrobenzene (L- = anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K-ex(Ca2+, 2HL) = 0.0 +/- 0.1. Further, the stability constant of the electroneutral complex species CaL2 in water-saturated nitrobenzene was calculated for a temperature of 25 degrees C : log beta(nb) (CaL2) = 11.0 +/- 0.2. From extraction experiments and gamma-activity measurements, the exchange extraction constantcorresponding to the general equilibrium Ca2+(aq) + 2HL(nb) double left right arrow CaL2(nb) + 2H(+)(aq) taking place in the two-phase water-nitrobenzene (L- = anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log K-ex(Ca2+, 2HL) = 0.0 +/- 0.1. Further, the stability constant of the electroneutral complex species CaL2 in water-saturated nitrobenzene was calculated for a temperature of 25 degrees C : log beta(nb) (CaL2) = 11.0 +/- 0.2.
dcterms:title
Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function
skos:prefLabel
Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function Solvent Extraction of Calcium into Nitrobenzene by Using an Anionic Ligand Based on Cobalt Bis(Dicarbollide) Anion with Covalently Bonded CMPO Function
skos:notation
RIV/46356088:_____/12:#0001252!RIV13-MPO-46356088
n6:predkladatel
n10:ico%3A46356088
n4:aktivita
n15:N n15:S
n4:aktivity
N, S
n4:cisloPeriodika
2
n4:dodaniDat
n5:2013
n4:domaciTvurceVysledku
n16:6994520
n4:druhVysledku
n17:J
n4:duvernostUdaju
n13:S
n4:entitaPredkladatele
n12:predkladatel
n4:idSjednocenehoVysledku
169156
n4:idVysledku
RIV/46356088:_____/12:#0001252
n4:jazykVysledku
n7:eng
n4:klicovaSlova
Calcium; anionic ligand with CMPO function; complexation; extraction and stability constants; water-nitrobenzene system
n4:klicoveSlovo
n8:Calcium n8:extraction%20and%20stability%20constants n8:anionic%20ligand%20with%20CMPO%20function n8:complexation n8:water-nitrobenzene%20system
n4:kodStatuVydavatele
SI - Slovinská republika
n4:kontrolniKodProRIV
[FC764126E135]
n4:nazevZdroje
Acta Chimica Slovenica
n4:obor
n11:CH
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
3
n4:rokUplatneniVysledku
n5:2012
n4:svazekPeriodika
59
n4:tvurceVysledku
Selucký, Pavel Makrlík, Emanuel
n4:wos
000305826700029
s:issn
1318-0207
s:numberOfPages
4