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Statements

Subject Item
n2:RIV%2F46356088%3A_____%2F12%3A%230001248%21RIV13-MPO-46356088
rdf:type
n11:Vysledek skos:Concept
dcterms:description
From extraction experiments and -activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+(aq) + CaL2(nb) ML2(nb) + Ca2+(aq) taking place in the two-phase water-nitrobenzene system (M2+ = Mg2+, Sr2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, , Co2+, Ni2+, Mn2+; = anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the electroneutral complex species ML2 in water-saturated nitrobenzene were calculated; they were found to increase in the following cation order: Sr2+ < Ba2+, Ni2+ < Mg2+ < Co2+ < Zn2+, Cd2+ < Mn2+ < Cu2+ < Pb2+ < . From extraction experiments and -activity measurements, the exchange extraction constants corresponding to the general equilibrium M2+(aq) + CaL2(nb) ML2(nb) + Ca2+(aq) taking place in the two-phase water-nitrobenzene system (M2+ = Mg2+, Sr2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, , Co2+, Ni2+, Mn2+; = anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the electroneutral complex species ML2 in water-saturated nitrobenzene were calculated; they were found to increase in the following cation order: Sr2+ < Ba2+, Ni2+ < Mg2+ < Co2+ < Zn2+, Cd2+ < Mn2+ < Cu2+ < Pb2+ < .
dcterms:title
Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function
skos:prefLabel
Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function Solvent extraction of some divalent metal cations into nitrobenzene by using an anionic ligand based on cobalt bis(dicarbollide) anion with covalently bonded CMPO function
skos:notation
RIV/46356088:_____/12:#0001248!RIV13-MPO-46356088
n11:predkladatel
n13:ico%3A46356088
n3:aktivita
n4:S n4:N
n3:aktivity
N, S
n3:cisloPeriodika
1
n3:dodaniDat
n5:2013
n3:domaciTvurceVysledku
n6:6994520
n3:druhVysledku
n17:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
169159
n3:idVysledku
RIV/46356088:_____/12:#0001248
n3:jazykVysledku
n12:eng
n3:klicovaSlova
Cobalt bis(dicarbollide) anion; Divalent metal cations; Extraction; Nitrobenzene; Stability constants
n3:klicoveSlovo
n8:Nitrobenzene n8:Cobalt%20bis%28dicarbollide%29%20anion n8:Stability%20constants n8:Divalent%20metal%20cations n8:Extraction
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[69E40729F0A1]
n3:nazevZdroje
Journal of Radioanalytical and Nuclear Chemistry
n3:obor
n15:CH
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n5:2012
n3:svazekPeriodika
293
n3:tvurceVysledku
Makrlík, Emanuel Selucký, Pavel
n3:wos
000305228200014
s:issn
0236-5731
s:numberOfPages
4
n10:doi
10.1007/s10967-012-1770-6