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Statements

Subject Item
n2:RIV%2F46356088%3A_____%2F11%3A%230001169%21RIV12-MPO-46356088
rdf:type
n9:Vysledek skos:Concept
dcterms:description
From extraction experiments and c-activity measurements, the extraction constants corresponding to the general equilibrium Eu(3+)(aq) + 3A(-)(aq) + L(nb) <-> EuL(3+)(nb) ? 3A(-)(nb) taking part in the two-phase waternitrobenzene system (A(-) = CF(3)SO(3)(-); L = p-tert-butylcalix[6] arene, p-tert-butylcalix[8] arene; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Further, the stability constants of the EuL(3+) complexes in nitrobenzene saturated with water were calculated for a temperature of 25 degrees C as log beta(nb)(EuL(3+)) = 6.4 +/- 0.1 (L = p-tert-butylcalix[6]arene) and log beta(nb)(EuL(3+)) = 11.3 +/- 0.1 (L = p-tert-butylcalix[8]arene). From extraction experiments and c-activity measurements, the extraction constants corresponding to the general equilibrium Eu(3+)(aq) + 3A(-)(aq) + L(nb) <-> EuL(3+)(nb) ? 3A(-)(nb) taking part in the two-phase waternitrobenzene system (A(-) = CF(3)SO(3)(-); L = p-tert-butylcalix[6] arene, p-tert-butylcalix[8] arene; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Further, the stability constants of the EuL(3+) complexes in nitrobenzene saturated with water were calculated for a temperature of 25 degrees C as log beta(nb)(EuL(3+)) = 6.4 +/- 0.1 (L = p-tert-butylcalix[6]arene) and log beta(nb)(EuL(3+)) = 11.3 +/- 0.1 (L = p-tert-butylcalix[8]arene).
dcterms:title
Solvent extraction of europium trifluoromethanesulfonate into nitrobenzene in the presence of p-tert-butylcalix[6]arene and p-tert-butylcalix[8] arene Solvent extraction of europium trifluoromethanesulfonate into nitrobenzene in the presence of p-tert-butylcalix[6]arene and p-tert-butylcalix[8] arene
skos:prefLabel
Solvent extraction of europium trifluoromethanesulfonate into nitrobenzene in the presence of p-tert-butylcalix[6]arene and p-tert-butylcalix[8] arene Solvent extraction of europium trifluoromethanesulfonate into nitrobenzene in the presence of p-tert-butylcalix[6]arene and p-tert-butylcalix[8] arene
skos:notation
RIV/46356088:_____/11:#0001169!RIV12-MPO-46356088
n9:predkladatel
n15:ico%3A46356088
n3:aktivita
n14:Z n14:S n14:N
n3:aktivity
N, S, Z(MSM4977751303)
n3:cisloPeriodika
1
n3:dodaniDat
n4:2012
n3:domaciTvurceVysledku
n12:6994520
n3:druhVysledku
n17:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
230559
n3:idVysledku
RIV/46356088:_____/11:#0001169
n3:jazykVysledku
n18:eng
n3:klicovaSlova
Extraction; Europium trifluoromethanesulfonate; nitrobenzene; Stability constants
n3:klicoveSlovo
n5:nitrobenzene n5:Europium%20trifluoromethanesulfonate n5:Stability%20constants n5:Extraction
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[00ECA2453519]
n3:nazevZdroje
Journal of Radioanalytical and Nuclear Chemistry
n3:obor
n7:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n4:2011
n3:svazekPeriodika
287
n3:tvurceVysledku
Selucký, Pavel
n3:wos
000286333400039
n3:zamer
n19:MSM4977751303
s:issn
0236-5731
s:numberOfPages
4
n11:doi
10.1007/s10967-010-0674-6