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Statements

Subject Item
n2:RIV%2F00216305%3A26620%2F14%3APU112373%21RIV15-MSM-26620___
rdf:type
skos:Concept n22:Vysledek
rdfs:seeAlso
http://ecst.ecsdl.org/content/63/1/145.abstract
dcterms:description
The tacit assumption in an electrochemical experiment is that a properly set up electrochemical cell, working electrode, counter electrode, reference electrode and a potentiostat, will perform an experiment by %22applying potential on the working electrode%22 without any need to consider the properties of the reference electrodes, the effect of electrochemistry on the counter electrode and the real properties of the potentiostat. While this is in first approximation a valid assumption, in the extremes it is also necessary to consider the other parts of the system. In this work we visit two interesting cases that may lead to experimental artifacts. The first is the effect of electrochemical solution changes during impedance measurement. The second is effect of the time constant of a reference electrode on an impedance measurement in an electrochemical cell. The tacit assumption in an electrochemical experiment is that a properly set up electrochemical cell, working electrode, counter electrode, reference electrode and a potentiostat, will perform an experiment by %22applying potential on the working electrode%22 without any need to consider the properties of the reference electrodes, the effect of electrochemistry on the counter electrode and the real properties of the potentiostat. While this is in first approximation a valid assumption, in the extremes it is also necessary to consider the other parts of the system. In this work we visit two interesting cases that may lead to experimental artifacts. The first is the effect of electrochemical solution changes during impedance measurement. The second is effect of the time constant of a reference electrode on an impedance measurement in an electrochemical cell.
dcterms:title
Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode
skos:prefLabel
Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode Electrochemistry in the Electrochemical Cells: There is More than Just the Working Electrode
skos:notation
RIV/00216305:26620/14:PU112373!RIV15-MSM-26620___
n3:aktivita
n4:P
n3:aktivity
P(ED1.1.00/02.0068)
n3:dodaniDat
n6:2015
n3:domaciTvurceVysledku
Vanýsek, Petr
n3:druhVysledku
n19:D
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
14124
n3:idVysledku
RIV/00216305:26620/14:PU112373
n3:jazykVysledku
n16:eng
n3:klicovaSlova
impedance, 3-electrode cell, potentiostat, experimental artifact,
n3:klicoveSlovo
n12:3-electrode%20cell n12:potentiostat n12:impedance n12:experimental%20artifact
n3:kontrolniKodProRIV
[E797965D344B]
n3:mistoKonaniAkce
Brno
n3:mistoVydani
Pennington, NJ
n3:nazevZdroje
15th International Conference on Advanced Batteries, Accumulators and Fuel Cells (ABAF 2014)
n3:obor
n18:CG
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:projekt
n14:ED1.1.00%2F02.0068
n3:rokUplatneniVysledku
n6:2014
n3:tvurceVysledku
Pilson, Kate-Leigh Vanýsek, Petr Tavassol, Hadi
n3:typAkce
n15:WRD
n3:zahajeniAkce
2014-08-24+02:00
s:numberOfPages
11
n20:doi
10.1149/06301.0145ecst
n9:hasPublisher
The Electrochemical Society
n5:isbn
978-1-62332-230-4
n8:organizacniJednotka
26620