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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F14%3A39898441%21RIV15-MSM-25310___
rdf:type
skos:Concept n13:Vysledek
dcterms:description
Five polymeric Mn(II) complexes with bridging carboxylato groups were prepared and structurally characterized. The bridging carboxylato ligand in double-chain coordination polymeric structures of [Mn(mu-3-NO(2)bz)(2) (bipy)](n)center dot nH(2)O, [Mn(mu-3,5-(NO2)(2)bz)(2)(bipy)](n), [Mn(mu-5-(NO2)sal)(2)(bipy)](n), and [Mn(mu-5-(NO2)sal)(2)(phen)](n), where 3-NO(2)bz(-) = 3-nitrobenzoate, 3,5-(NO2)(2)bz(-) = 3,5-dinitrobenzoate, 5-(NO2)sal(-) = 5-nitrosalicylate, bipy = 2,2'-bipyridine and phen = 1,10-phenanthroline, exhibits the syn-anti bidentate bridging mode. The Mn(II) atom in the coordination polymer [Mn(mu-4-NO(2)bz)(4-NO(2)bz)(phen)(H2O)](n), where 4-NO(2)b(z) = 3-nitrobenzoate, is coordinated by terminal carboxylato groups in the syn monodentate mode but two Mn(II) atoms are connected with bridging 4-nitrobenzoate ligands in the anti-anti bidentate bridging mode. The magnetic susceptibility and magnetization data confirm that weak exchange interactions of an antiferromagnetic nature apply in these complexes. Five polymeric Mn(II) complexes with bridging carboxylato groups were prepared and structurally characterized. The bridging carboxylato ligand in double-chain coordination polymeric structures of [Mn(mu-3-NO(2)bz)(2) (bipy)](n)center dot nH(2)O, [Mn(mu-3,5-(NO2)(2)bz)(2)(bipy)](n), [Mn(mu-5-(NO2)sal)(2)(bipy)](n), and [Mn(mu-5-(NO2)sal)(2)(phen)](n), where 3-NO(2)bz(-) = 3-nitrobenzoate, 3,5-(NO2)(2)bz(-) = 3,5-dinitrobenzoate, 5-(NO2)sal(-) = 5-nitrosalicylate, bipy = 2,2'-bipyridine and phen = 1,10-phenanthroline, exhibits the syn-anti bidentate bridging mode. The Mn(II) atom in the coordination polymer [Mn(mu-4-NO(2)bz)(4-NO(2)bz)(phen)(H2O)](n), where 4-NO(2)b(z) = 3-nitrobenzoate, is coordinated by terminal carboxylato groups in the syn monodentate mode but two Mn(II) atoms are connected with bridging 4-nitrobenzoate ligands in the anti-anti bidentate bridging mode. The magnetic susceptibility and magnetization data confirm that weak exchange interactions of an antiferromagnetic nature apply in these complexes.
dcterms:title
Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties
skos:prefLabel
Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties Manganese(II) one-dimensional coordination polymers with nitrobenzoato or nitrosalicylato bridges: Syntheses, crystal structures, and magnetic properties
skos:notation
RIV/00216275:25310/14:39898441!RIV15-MSM-25310___
n3:aktivita
n10:I
n3:aktivity
I
n3:cisloPeriodika
September
n3:dodaniDat
n4:2015
n3:domaciTvurceVysledku
n16:5804620
n3:druhVysledku
n11:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
27125
n3:idVysledku
RIV/00216275:25310/14:39898441
n3:jazykVysledku
n15:eng
n3:klicovaSlova
Coordination polymer; EPR spectroscopy; Magnetic properties; Crystal structures; Manganese
n3:klicoveSlovo
n5:EPR%20spectroscopy n5:Manganese n5:Crystal%20structures n5:Magnetic%20properties n5:Coordination%20polymer
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[00E2CAF90DBD]
n3:nazevZdroje
Polyhedron
n3:obor
n17:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
9
n3:rokUplatneniVysledku
n4:2014
n3:svazekPeriodika
79
n3:tvurceVysledku
Valigura, Dusan Moncol, Jan Martiskova, Alena Cechova, Danica Valko, Marian Padělková, Zdeňka Dlhan, L'ubor Gala, Lukas Boca, Roman
n3:wos
000340313800016
s:issn
0277-5387
s:numberOfPages
9
n8:doi
10.1016/j.poly.2014.05.005
n12:organizacniJednotka
25310