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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F14%3A39898096%21RIV15-MSM-25310___
rdf:type
n11:Vysledek skos:Concept
dcterms:description
The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do not affect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography. The reactivity of cyclopentadienyl and indenyl molybdenum(II) complexes [(h5-Cp')Mo(CO)2(NCMe)2] [BF4] (Cp' = Cp, Ind, 1,3-Ph2C9H5) with a series of planar N,N,N-chelating ligands was scrutinized. In particular cases a spontaneous release of carbon monoxide to give [(h5-Cp')Mo(CO)(k3-N,N,NL)][BF4] depending on several factors including the basicity of the tridentate ligand as well as the nature of the starting molybdenum(II) compound. This behaviour strongly contrasts with tripodal ligands those do not affect cis-Mo(CO)2 moiety even upon tridentate coordination. All structure types, discussed in this work, were elucidated by the spectroscopic measurements as well as by the X-ray crystallography.
dcterms:title
Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands
skos:prefLabel
Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands Cyclopentadienyl and indenyl molybdenum(II) complexes bearing planar N,N,N-chelating ligands
skos:notation
RIV/00216275:25310/14:39898096!RIV15-MSM-25310___
n5:aktivita
n7:I
n5:aktivity
I
n5:cisloPeriodika
December
n5:dodaniDat
n10:2015
n5:domaciTvurceVysledku
n6:7774214 n6:6665977 n6:5804620 n6:5024927
n5:druhVysledku
n9:J
n5:duvernostUdaju
n13:S
n5:entitaPredkladatele
n17:predkladatel
n5:idSjednocenehoVysledku
9516
n5:idVysledku
RIV/00216275:25310/14:39898096
n5:jazykVysledku
n18:eng
n5:klicovaSlova
CO-releasing molecule; Infrared spectroscopy; Pincer ligands; Indenyl effect; Molybdenum compounds
n5:klicoveSlovo
n12:Pincer%20ligands n12:Molybdenum%20compounds n12:CO-releasing%20molecule n12:Indenyl%20effect n12:Infrared%20spectroscopy
n5:kodStatuVydavatele
CH - Švýcarská konfederace
n5:kontrolniKodProRIV
[8AFDCEB2A408]
n5:nazevZdroje
Journal of Organometallic Chemistry
n5:obor
n14:CA
n5:pocetDomacichTvurcuVysledku
4
n5:pocetTvurcuVysledku
4
n5:rokUplatneniVysledku
n10:2014
n5:svazekPeriodika
772-773
n5:tvurceVysledku
Vinklárek, Jaromír Honzíčková, Iva Honzíček, Jan Růžičková, Zdeňka
n5:wos
000344470100040
s:issn
0022-328X
s:numberOfPages
8
n16:doi
10.1016/j.jorganchem.2014.09.028
n15:organizacniJednotka
25310