This HTML5 document contains 48 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n12http://localhost/temp/predkladatel/
n5http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n18http://linked.opendata.cz/resource/domain/vavai/subjekt/
n17http://linked.opendata.cz/ontology/domain/vavai/
n19http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F00216275%3A25310%2F13%3A39896296%21RIV14-MSM-25310___/
shttp://schema.org/
rdfshttp://www.w3.org/2000/01/rdf-schema#
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n14http://bibframe.org/vocab/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n6http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n20http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n15http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n13http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n16http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n10http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n9http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F13%3A39896296%21RIV14-MSM-25310___
rdf:type
skos:Concept n17:Vysledek
rdfs:seeAlso
http://pubs.acs.org/doi/abs/10.1021/om400082t
dcterms:description
Treatment of the neutral 2-[C(CH3)=N(C6H3-2,6-Pr-i(2))]-6-(CH3O)C6H3N ligand (hereafter assigned as L) with SnCl2 and GeCl2 provided the ionic germanium(II) and tin(II) complexes [(LGeCl)-Cl-II](+)[(GeCl3)-Cl-II](-) (1) and [(LSnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) (2), respectively, as the result of spontaneous dissociation of ECl2 (E = Ge, Sn). The cationic parts [(LECl)-Cl-II](+) of 1 and 2 contain three-coordinated germanium(II) and tin(II) atoms. In comparison, treatment of the ligand L with GeCl4, and SnBr4 yielded the germanium(IV) and tin(IV) complexes LGeCl4 (3) and LSnBr4 (4), respectively, and no dissociation process was observed. Compounds 1-4 were characterized by means of elemental analyses, H-1, C-13, and Sn-119 NMR spectroscopies, and single-crystal X-ray diffraction analysis in (compounds 1 and 4). Treatment of the neutral 2-[C(CH3)=N(C6H3-2,6-Pr-i(2))]-6-(CH3O)C6H3N ligand (hereafter assigned as L) with SnCl2 and GeCl2 provided the ionic germanium(II) and tin(II) complexes [(LGeCl)-Cl-II](+)[(GeCl3)-Cl-II](-) (1) and [(LSnCl)-Cl-II](+)[(SnCl3)-Cl-II](-) (2), respectively, as the result of spontaneous dissociation of ECl2 (E = Ge, Sn). The cationic parts [(LECl)-Cl-II](+) of 1 and 2 contain three-coordinated germanium(II) and tin(II) atoms. In comparison, treatment of the ligand L with GeCl4, and SnBr4 yielded the germanium(IV) and tin(IV) complexes LGeCl4 (3) and LSnBr4 (4), respectively, and no dissociation process was observed. Compounds 1-4 were characterized by means of elemental analyses, H-1, C-13, and Sn-119 NMR spectroscopies, and single-crystal X-ray diffraction analysis in (compounds 1 and 4).
dcterms:title
Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand
skos:prefLabel
Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand Stabilization of Three-Coordinated Germanium(II) and Tin(II) Cations by a Neutral Chelating Ligand
skos:notation
RIV/00216275:25310/13:39896296!RIV14-MSM-25310___
n17:predkladatel
n18:orjk%3A25310
n3:aktivita
n15:S n15:I
n3:aktivity
I, S
n3:cisloPeriodika
6
n3:dodaniDat
n9:2014
n3:domaciTvurceVysledku
n5:6249442 n5:8975671 n5:1403753 n5:5107962
n3:druhVysledku
n16:J
n3:duvernostUdaju
n20:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
107409
n3:idVysledku
RIV/00216275:25310/13:39896296
n3:jazykVysledku
n13:eng
n3:klicovaSlova
activation; coordination; complexes; tin cations
n3:klicoveSlovo
n6:activation n6:coordination n6:complexes n6:tin%20cations
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[25442B1E420F]
n3:nazevZdroje
Organometallics
n3:obor
n10:CA
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n9:2013
n3:svazekPeriodika
32
n3:tvurceVysledku
Bouška, Marek Jambor, Roman Růžička, Aleš Dostál, Libor
n3:wos
000316773800054
s:issn
0276-7333
s:numberOfPages
5
n14:doi
10.1021/om400082t
n12:organizacniJednotka
25310