This HTML5 document contains 52 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n18http://localhost/temp/predkladatel/
n19http://linked.opendata.cz/resource/domain/vavai/projekt/
n5http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n8http://linked.opendata.cz/resource/domain/vavai/subjekt/
n7http://linked.opendata.cz/ontology/domain/vavai/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n14http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F00216275%3A25310%2F13%3A39896115%21RIV14-GA0-25310___/
n10http://bibframe.org/vocab/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n6http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n17http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n16http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n9http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n20http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n11http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n13http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F13%3A39896115%21RIV14-GA0-25310___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Fifteen model charge-transfer chromophores with ferrocene donors, NO2 acceptors, and 1,4-phenylene and 2,5-thienylene p-linkers were synthesized and their properties investigated by X-ray analysis, electrochemistry, absorption spectra, and DFT calculations. Structure?property relationships were further evaluated to answer the question of suitability of the p-linkers in the construction of chromophore backbone. Gradual replacement of 1,4-phenylene with 2,5-thienylene and p-linker extension resulted in a lower HOMO?LUMO gap, a bathochromic shift of both charge-transfer bands, and overall planarization of the molecule. Hence, thiophene, when incorporated into a chromophore backbone, is a more polarizable moiety that allows very efficient intramolecular charge transfer. Fifteen model charge-transfer chromophores with ferrocene donors, NO2 acceptors, and 1,4-phenylene and 2,5-thienylene p-linkers were synthesized and their properties investigated by X-ray analysis, electrochemistry, absorption spectra, and DFT calculations. Structure?property relationships were further evaluated to answer the question of suitability of the p-linkers in the construction of chromophore backbone. Gradual replacement of 1,4-phenylene with 2,5-thienylene and p-linker extension resulted in a lower HOMO?LUMO gap, a bathochromic shift of both charge-transfer bands, and overall planarization of the molecule. Hence, thiophene, when incorporated into a chromophore backbone, is a more polarizable moiety that allows very efficient intramolecular charge transfer.
dcterms:title
1,4-Phenylene and 2,5-Thienylene p-Linkers in Charge-Transfer Chromophores 1,4-Phenylene and 2,5-Thienylene p-Linkers in Charge-Transfer Chromophores
skos:prefLabel
1,4-Phenylene and 2,5-Thienylene p-Linkers in Charge-Transfer Chromophores 1,4-Phenylene and 2,5-Thienylene p-Linkers in Charge-Transfer Chromophores
skos:notation
RIV/00216275:25310/13:39896115!RIV14-GA0-25310___
n7:predkladatel
n8:orjk%3A25310
n3:aktivita
n16:P n16:I
n3:aktivity
I, P(GAP106/12/0392)
n3:cisloPeriodika
5
n3:dodaniDat
n13:2014
n3:domaciTvurceVysledku
n5:7182554 n5:1821199 n5:9403361 n5:7102305 n5:5107962
n3:druhVysledku
n11:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
119627
n3:idVysledku
RIV/00216275:25310/13:39896115
n3:jazykVysledku
n9:eng
n3:klicovaSlova
thiophenes; p-linkers; DFT calculations; chromophores; charge transfer
n3:klicoveSlovo
n6:p-linkers n6:DFT%20calculations n6:thiophenes n6:chromophores n6:charge%20transfer
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[BD4E3CF486DA]
n3:nazevZdroje
Asian Journal of Organic Chemistry
n3:obor
n20:CC
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
6
n3:projekt
n19:GAP106%2F12%2F0392
n3:rokUplatneniVysledku
n13:2013
n3:svazekPeriodika
2
n3:tvurceVysledku
Růžička, Aleš Kuznik, Wojciech Bureš, Filip Mikysek, Tomáš Opršal, Jakub Kulhánek, Jiří
n3:wos
000325988200010
s:issn
2193-5815
s:numberOfPages
10
n10:doi
10.1002/ajoc.201300063
n18:organizacniJednotka
25310