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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F12%3A39895760%21RIV13-GA0-25310___
rdf:type
skos:Concept n9:Vysledek
rdfs:seeAlso
http://onlinelibrary.wiley.com/doi/10.1002/chem.201102016/pdf
dcterms:description
A simple and high-yield route to a series of tricarbollide compounds 8-R-nido-7,8,9-C3B8H11 and [8-R-nido-7,8,9-C3B8H10]? (exemplified by R=Me, Ph, and 1-naphthyl) was developed. The method is based on a new type of C-insertion cross-coupling through skeletal alkylcarbonation (SAC) reactions between acyl chlorides (RCOCl) and the arachno-6,9-C2B8H14 carborane. A simple and high-yield route to a series of tricarbollide compounds 8-R-nido-7,8,9-C3B8H11 and [8-R-nido-7,8,9-C3B8H10]? (exemplified by R=Me, Ph, and 1-naphthyl) was developed. The method is based on a new type of C-insertion cross-coupling through skeletal alkylcarbonation (SAC) reactions between acyl chlorides (RCOCl) and the arachno-6,9-C2B8H14 carborane.
dcterms:title
Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14) Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14)
skos:prefLabel
Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14) Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14)
skos:notation
RIV/00216275:25310/12:39895760!RIV13-GA0-25310___
n9:predkladatel
n10:orjk%3A25310
n5:aktivita
n15:Z n15:I n15:S n15:P
n5:aktivity
I, P(GAP207/11/0705), P(LC523), S, Z(AV0Z40320502), Z(MSM0021627501)
n5:cisloPeriodika
47
n5:dodaniDat
n16:2013
n5:domaciTvurceVysledku
n14:5107962 n14:5804620 n14:6951082
n5:druhVysledku
n18:J
n5:duvernostUdaju
n7:S
n5:entitaPredkladatele
n11:predkladatel
n5:idSjednocenehoVysledku
229632
n5:idVysledku
RIV/00216275:25310/12:39895760
n5:jazykVysledku
n21:eng
n5:klicovaSlova
synthetic methods; cross-coupling; carboranes; boranes; acyl chlorides
n5:klicoveSlovo
n13:carboranes n13:cross-coupling n13:boranes n13:acyl%20chlorides n13:synthetic%20methods
n5:kodStatuVydavatele
DE - Spolková republika Německo
n5:kontrolniKodProRIV
[1DF4B58A2D74]
n5:nazevZdroje
Chemistry - A European Journal
n5:obor
n17:CA
n5:pocetDomacichTvurcuVysledku
3
n5:pocetTvurcuVysledku
7
n5:projekt
n8:LC523 n8:GAP207%2F11%2F0705
n5:rokUplatneniVysledku
n16:2012
n5:svazekPeriodika
17
n5:tvurceVysledku
Holub, Josef Padělková, Zdeňka Bakardjiev, Mario Olejník, Roman Švec, Petr Štíbr, Bohumil Růžička, Aleš
n5:wos
000298058500009
n5:zamer
n12:AV0Z40320502 n12:MSM0021627501
s:issn
0947-6539
s:numberOfPages
4
n20:doi
10.1002/chem.201102016
n3:organizacniJednotka
25310