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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F12%3A39895564%21RIV13-GA0-25310___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Organoantimony(III) and organobismuth(III) oxides (LMO)(2) (where L is the NCN-chelating ligand C6H3-2,6-(CH2NMe2)(2) and M = Sb (1), Bi (2)) reacted smoothly with arsenic oxides As2O5 and As2O3 to form the molecular oxides [(LM)(3)(AsO4)(2)] and [(LM)(2)(As2O5)] (where M = Sb (3, 5), Bi (4, 6)). All compounds were characterized by electrospray ionization (ESI) mass spectrometry, nuclear magnetic resonance (NMR) spectroscopy, and, in the case of and 6, single-crystal X-ray diffraction (XRD) analyses. Compound 3 formed two conformational isomers in a benzene or chloroform solution, as confirmed by H-1 and C-13 NMR spectroscopy. As in the case of 3, 5 also formed conformational isomers in a benzene solution, whereas the bismuth analogue 6 was unstable in solution. The stabilities of the three possible conformers of 5 were studied by density functional theory (DFT) calculations. Organoantimony(III) and organobismuth(III) oxides (LMO)(2) (where L is the NCN-chelating ligand C6H3-2,6-(CH2NMe2)(2) and M = Sb (1), Bi (2)) reacted smoothly with arsenic oxides As2O5 and As2O3 to form the molecular oxides [(LM)(3)(AsO4)(2)] and [(LM)(2)(As2O5)] (where M = Sb (3, 5), Bi (4, 6)). All compounds were characterized by electrospray ionization (ESI) mass spectrometry, nuclear magnetic resonance (NMR) spectroscopy, and, in the case of and 6, single-crystal X-ray diffraction (XRD) analyses. Compound 3 formed two conformational isomers in a benzene or chloroform solution, as confirmed by H-1 and C-13 NMR spectroscopy. As in the case of 3, 5 also formed conformational isomers in a benzene solution, whereas the bismuth analogue 6 was unstable in solution. The stabilities of the three possible conformers of 5 were studied by density functional theory (DFT) calculations.
dcterms:title
Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic
skos:prefLabel
Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic Reactivity of NCN-Chelated (NCN = C6H3-2,6-(CH2NMe2)(2)) Antimony(III) and Bismuth(III) Oxides toward Oxides of Arsenic
skos:notation
RIV/00216275:25310/12:39895564!RIV13-GA0-25310___
n7:predkladatel
n17:orjk%3A25310
n3:aktivita
n4:P n4:I n4:S
n3:aktivity
I, P(GAP106/10/0443), S
n3:cisloPeriodika
5
n3:dodaniDat
n8:2013
n3:domaciTvurceVysledku
n12:1403753 n12:5107962 n12:3180409 n12:6345883 n12:8975671 n12:7296126
n3:druhVysledku
n19:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
164202
n3:idVysledku
RIV/00216275:25310/12:39895564
n3:jazykVysledku
n20:eng
n3:klicovaSlova
PH; ORGANOANTIMONY(III); ELEMENTS; CRYSTAL-STRUCTURES; GAUSSIAN-BASIS SETS; CORRELATED MOLECULAR CALCULATIONS; BOND COVALENT RADII
n3:klicoveSlovo
n11:CRYSTAL-STRUCTURES n11:BOND%20COVALENT%20RADII n11:CORRELATED%20MOLECULAR%20CALCULATIONS n11:GAUSSIAN-BASIS%20SETS n11:ELEMENTS n11:PH n11:ORGANOANTIMONY%28III%29
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[CE1C53A293EC]
n3:nazevZdroje
Organometallics
n3:obor
n14:CA
n3:pocetDomacichTvurcuVysledku
6
n3:pocetTvurcuVysledku
7
n3:projekt
n18:GAP106%2F10%2F0443
n3:rokUplatneniVysledku
n8:2012
n3:svazekPeriodika
31
n3:tvurceVysledku
Dostál, Libor Růžička, Aleš Jirásko, Robert De Proft, Frank Lyčka, Antonín Svoboda, Tomáš Jambor, Roman
n3:wos
000301331200019
s:issn
0276-7333
s:numberOfPages
5
n6:doi
10.1021/om201025d
n16:organizacniJednotka
25310