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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F12%3A39895559%21RIV13-GA0-25310___
rdf:type
n6:Vysledek skos:Concept
dcterms:description
A set of organogold(I) compounds L14Au(PPh3), where L1 = [o-C6H4(CH=NC6H3iPr2-2,6)] (1), L2 = {o,o-C6H3[C(Me)=NC6H3Me2-2,6]2} (2), L3 = [o,o'-C6H3(CH2OMe)(CH2NMe2)] (3), L4 = [o,o-C6H3(CH2OMe)2] (4), were synthesized by the reaction of parent organolithium derivatives L14Li with [AuCl(PPh3)] in good yields. The molecular structures of 14 were characterized by ESI mass spectrometry and 1H NMR, 13C NMR and 31P NMR spectroscopy, and their structures in the solid state were determined using single-crystal X-ray diffraction analyses. The transmetalation potential of 14 was tested by the reaction with either [PdCl2(CH3CN)2] or [PtCl2(Et2S)2] complexes. While the reaction of compounds 1 and 2 proceeded smoothly with the formation of the desired transition-metal complexes, i.e. (L1PdCl)2 (5), L1PtCl(Et2S) (6) and L2MCl [M = Pd (7) or Pt (8). In the case of the O,C,N- and O,C,O-chelated derivatives 3 and 4 only the platinum(II) compounds L3PtCl(PPh3) (9) and L4PtCl(Et2S)2 (10) could be isolated after the reaction, as a result of the labile behaviour of the corresponding palladium compounds. All derivatives 510 were characterized by the help of ESI mass spectrometry and 1H NMR, 13C NMR and 31P NMR spectroscopy, and in the case of compounds 57 and 9 using single-crystal X-ray diffraction analyses. A set of organogold(I) compounds L14Au(PPh3), where L1 = [o-C6H4(CH=NC6H3iPr2-2,6)] (1), L2 = {o,o-C6H3[C(Me)=NC6H3Me2-2,6]2} (2), L3 = [o,o'-C6H3(CH2OMe)(CH2NMe2)] (3), L4 = [o,o-C6H3(CH2OMe)2] (4), were synthesized by the reaction of parent organolithium derivatives L14Li with [AuCl(PPh3)] in good yields. The molecular structures of 14 were characterized by ESI mass spectrometry and 1H NMR, 13C NMR and 31P NMR spectroscopy, and their structures in the solid state were determined using single-crystal X-ray diffraction analyses. The transmetalation potential of 14 was tested by the reaction with either [PdCl2(CH3CN)2] or [PtCl2(Et2S)2] complexes. While the reaction of compounds 1 and 2 proceeded smoothly with the formation of the desired transition-metal complexes, i.e. (L1PdCl)2 (5), L1PtCl(Et2S) (6) and L2MCl [M = Pd (7) or Pt (8). In the case of the O,C,N- and O,C,O-chelated derivatives 3 and 4 only the platinum(II) compounds L3PtCl(PPh3) (9) and L4PtCl(Et2S)2 (10) could be isolated after the reaction, as a result of the labile behaviour of the corresponding palladium compounds. All derivatives 510 were characterized by the help of ESI mass spectrometry and 1H NMR, 13C NMR and 31P NMR spectroscopy, and in the case of compounds 57 and 9 using single-crystal X-ray diffraction analyses.
dcterms:title
Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds
skos:prefLabel
Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds
skos:notation
RIV/00216275:25310/12:39895559!RIV13-GA0-25310___
n6:predkladatel
n9:orjk%3A25310
n4:aktivita
n7:I n7:P
n4:aktivity
I, P(GAP207/10/0215)
n4:cisloPeriodika
15
n4:dodaniDat
n15:2013
n4:domaciTvurceVysledku
n8:6410065 n8:1403753 n8:5107962 n8:5347343 n8:8975671 n8:6345883
n4:druhVysledku
n12:J
n4:duvernostUdaju
n20:S
n4:entitaPredkladatele
n14:predkladatel
n4:idSjednocenehoVysledku
173005
n4:idVysledku
RIV/00216275:25310/12:39895559
n4:jazykVysledku
n10:eng
n4:klicovaSlova
Compounds; OrganogoldI; C,Y-Chelated; Various; Activity; Transmetalation; and; Structure; Synthesis
n4:klicoveSlovo
n5:and n5:Compounds n5:Transmetalation n5:Activity n5:Y-Chelated n5:OrganogoldI n5:Structure n5:Various n5:Synthesis n5:C
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[7F19DC31D00A]
n4:nazevZdroje
European Journal of Inorganic Chemistry
n4:obor
n11:CA
n4:pocetDomacichTvurcuVysledku
6
n4:pocetTvurcuVysledku
6
n4:projekt
n18:GAP207%2F10%2F0215
n4:rokUplatneniVysledku
n15:2012
n4:svazekPeriodika
Neuveden
n4:tvurceVysledku
Růžička, Aleš Jambor, Roman Jirásko, Robert Holeček, Jaroslav Dostál, Libor Hejda, Martin
n4:wos
000303987800011
s:issn
1434-1948
s:numberOfPages
10
n17:doi
10.1002/ejic.201200152
n13:organizacniJednotka
25310