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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F12%3A39895488%21RIV13-GA0-25310___
rdf:type
n10:Vysledek skos:Concept
dcterms:description
A micellar electrokinetic capillary chromatography method for separation of phenolic acids and flavonoids suitable for application in two-dimensional system in combination with gradient elution reversed-phase liquid chromatography was developed. The influence of type of surfactant on the separation selectivity in background electrolytes with different concentration of acetonitrile was studied. The critical micelle concentration of homological series of sodium alkyl sulfates and migration times of their micelles were determined. The sodium alkyl sulfates with octyl- to octadecyl- alkyl chains were used to achieve the similar time of analysis and similar separation selectivity in background electrolytes with concentration of acetonitrile up to the 20% (v/v). A micellar electrokinetic capillary chromatography method for separation of phenolic acids and flavonoids suitable for application in two-dimensional system in combination with gradient elution reversed-phase liquid chromatography was developed. The influence of type of surfactant on the separation selectivity in background electrolytes with different concentration of acetonitrile was studied. The critical micelle concentration of homological series of sodium alkyl sulfates and migration times of their micelles were determined. The sodium alkyl sulfates with octyl- to octadecyl- alkyl chains were used to achieve the similar time of analysis and similar separation selectivity in background electrolytes with concentration of acetonitrile up to the 20% (v/v).
dcterms:title
Optimization of MEKC Separation Selectivity of Phenolic Compounds Using Homological Series of Anionic Surfactants Optimization of MEKC Separation Selectivity of Phenolic Compounds Using Homological Series of Anionic Surfactants
skos:prefLabel
Optimization of MEKC Separation Selectivity of Phenolic Compounds Using Homological Series of Anionic Surfactants Optimization of MEKC Separation Selectivity of Phenolic Compounds Using Homological Series of Anionic Surfactants
skos:notation
RIV/00216275:25310/12:39895488!RIV13-GA0-25310___
n10:predkladatel
n11:orjk%3A25310
n3:aktivita
n12:P
n3:aktivity
P(GAP206/12/0398)
n3:dodaniDat
n8:2013
n3:domaciTvurceVysledku
n15:2967391 n15:8169314 n15:4487877 n15:7835604
n3:druhVysledku
n4:D
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
156965
n3:idVysledku
RIV/00216275:25310/12:39895488
n3:jazykVysledku
n6:eng
n3:klicovaSlova
critical micelle concentration; anionic surfactants; separation selectivity; micellar electrokinetic capillary chromatography
n3:klicoveSlovo
n20:separation%20selectivity n20:critical%20micelle%20concentration n20:micellar%20electrokinetic%20capillary%20chromatography n20:anionic%20surfactants
n3:kontrolniKodProRIV
[0B48DB54C0BF]
n3:mistoKonaniAkce
Brno
n3:mistoVydani
Brno
n3:nazevZdroje
CECE 2012: 9th International Interdisciplinary Meeting on Bioanalysis
n3:obor
n5:CB
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n14:GAP206%2F12%2F0398
n3:rokUplatneniVysledku
n8:2012
n3:tvurceVysledku
Jandera, Pavel Fischer, Jan Česla, Petr Váňová, Jana
n3:typAkce
n21:WRD
n3:zahajeniAkce
2012-10-31+01:00
s:numberOfPages
7
n7:hasPublisher
Ústav analytické chemie AV ČR, v. v. i.
n16:isbn
978-80-904959-1-3
n13:organizacniJednotka
25310