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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F12%3A39895171%21RIV13-MSM-25310___
rdf:type
n9:Vysledek skos:Concept
dcterms:description
A new procedure was elaborated to determine trace bismuth(III) using an anodic stripping square-wave voltammetry at the antimony film carbon paste electrode (SbF-CPE). The method is realized in highly acidic medium of hydrochloric acid in which antimony peak is negligible, and apparently catalyzed by presence of cadmium(II), thus allowing the determination at ppb levels. Calibration dependence was linear up to 110 ppb Bi with a detection limit (3 sigma) of 1.55 ppb. Applicability of the method was tested on the real sample of river water. A new procedure was elaborated to determine trace bismuth(III) using an anodic stripping square-wave voltammetry at the antimony film carbon paste electrode (SbF-CPE). The method is realized in highly acidic medium of hydrochloric acid in which antimony peak is negligible, and apparently catalyzed by presence of cadmium(II), thus allowing the determination at ppb levels. Calibration dependence was linear up to 110 ppb Bi with a detection limit (3 sigma) of 1.55 ppb. Applicability of the method was tested on the real sample of river water.
dcterms:title
Determination of Trace Bismuth(III) by Stripping Voltammetry at Antimony-Coated Carbon Paste Electrode Determination of Trace Bismuth(III) by Stripping Voltammetry at Antimony-Coated Carbon Paste Electrode
skos:prefLabel
Determination of Trace Bismuth(III) by Stripping Voltammetry at Antimony-Coated Carbon Paste Electrode Determination of Trace Bismuth(III) by Stripping Voltammetry at Antimony-Coated Carbon Paste Electrode
skos:notation
RIV/00216275:25310/12:39895171!RIV13-MSM-25310___
n9:predkladatel
n10:orjk%3A25310
n3:aktivita
n17:P n17:I
n3:aktivity
I, P(LC06035)
n3:cisloPeriodika
1
n3:dodaniDat
n4:2013
n3:domaciTvurceVysledku
n14:6143083 Ashrafi, Amirmansoor
n3:druhVysledku
n13:J
n3:duvernostUdaju
n6:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
130662
n3:idVysledku
RIV/00216275:25310/12:39895171
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Cd(II)-assisted catalysis; carbon paste electrode; antimony film electrode; stripping voltammetry; bismuth(III) determination
n3:klicoveSlovo
n5:bismuth%28III%29%20determination n5:carbon%20paste%20electrode n5:Cd%28II%29-assisted%20catalysis n5:stripping%20voltammetry n5:antimony%20film%20electrode
n3:kodStatuVydavatele
CS - Státní svaz Srbska a Černé Hory
n3:kontrolniKodProRIV
[1EAD7225926C]
n3:nazevZdroje
International Journal of Electrochemical Science
n3:obor
n8:CG
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n11:LC06035
n3:rokUplatneniVysledku
n4:2012
n3:svazekPeriodika
7
n3:tvurceVysledku
Vytřas, Karel Ashrafi, Amirmansoor
n3:wos
000302723700006
s:issn
1452-3981
s:numberOfPages
9
n12:organizacniJednotka
25310