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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F12%3A39894829%21RIV13-GA0-25310___
rdf:type
skos:Concept n14:Vysledek
dcterms:description
The preparation of the secondary phosphane (Ph){C6H3-2,6-(CH2NMe2)2}PH (1), a potentially base-stabilized ligand, and the sterically protected carbaborane-based phosphane (o-CH3C2B10H10)2PH (2) is reported. Reaction of Sn{N(SiMe3)}2 with 1 gives the diphosphastannylene [(Ph){(C6H3-2,6-CH2NMe2)2}P]2Sn (3) in high yield. In contrast, the room-temperature reaction of 2 with Sn{N(SiMe2)}2 does not proceed. By applying elevated temperatures, the heteroleptic amidophosphastannylene {(o-CH3C2B10H10)2P}{(SiMe3)2N}Sn (4) was formed, instead of the expected diphosphastannylene {(o-CH3C2B10H10)2P}2Sn. The thermal decomposition of compounds 3 and 4 was also studied. The thermal decomposition of 3 produced the new phosphorusphosphorus-bonded compound 5, an unprecedented 1,2-diphosphol-type molecule. The preparation of the secondary phosphane (Ph){C6H3-2,6-(CH2NMe2)2}PH (1), a potentially base-stabilized ligand, and the sterically protected carbaborane-based phosphane (o-CH3C2B10H10)2PH (2) is reported. Reaction of Sn{N(SiMe3)}2 with 1 gives the diphosphastannylene [(Ph){(C6H3-2,6-CH2NMe2)2}P]2Sn (3) in high yield. In contrast, the room-temperature reaction of 2 with Sn{N(SiMe2)}2 does not proceed. By applying elevated temperatures, the heteroleptic amidophosphastannylene {(o-CH3C2B10H10)2P}{(SiMe3)2N}Sn (4) was formed, instead of the expected diphosphastannylene {(o-CH3C2B10H10)2P}2Sn. The thermal decomposition of compounds 3 and 4 was also studied. The thermal decomposition of 3 produced the new phosphorusphosphorus-bonded compound 5, an unprecedented 1,2-diphosphol-type molecule.
dcterms:title
Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling? Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling?
skos:prefLabel
Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling? Diphosphastannylenes: Precursors for Phosphorus-Phosphorus Coupling?
skos:notation
RIV/00216275:25310/12:39894829!RIV13-GA0-25310___
n14:predkladatel
n15:orjk%3A25310
n3:aktivita
n16:I n16:S n16:P
n3:aktivity
I, P(GAP207/10/0215), S
n3:cisloPeriodika
18
n3:dodaniDat
n5:2013
n3:domaciTvurceVysledku
n11:1768220 n11:8975671 n11:5107962 n11:1403753
n3:druhVysledku
n19:J
n3:duvernostUdaju
n20:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
131400
n3:idVysledku
RIV/00216275:25310/12:39894829
n3:jazykVysledku
n12:eng
n3:klicovaSlova
X ray diffraction; NMR spectroscopy; P-P coupling; P ligands; Tin
n3:klicoveSlovo
n10:P%20ligands n10:Tin n10:X%20ray%20diffraction n10:NMR%20spectroscopy n10:P-P%20coupling
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[7229D13DFB59]
n3:nazevZdroje
European Journal of Inorganic Chemistry
n3:obor
n8:CA
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n13:GAP207%2F10%2F0215
n3:rokUplatneniVysledku
n5:2012
n3:svazekPeriodika
2012
n3:tvurceVysledku
Dostál, Libor Růžička, Aleš Jambor, Roman Řezníček, Tomáš
n3:wos
000305122000003
s:issn
1434-1948
s:numberOfPages
5
n9:doi
10.1002/ejic.201200375
n17:organizacniJednotka
25310