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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F11%3A39892629%21RIV12-GA0-25310___
rdf:type
skos:Concept n7:Vysledek
dcterms:description
The polarity of (poly)methacrylate monolithic capillary columns was varied by using alkylmethacrylate monomers with butyl, cyclohexyl, 2-ethylhexyl, lauryl, and stearyl functional groups in the polymerization mixture. The hydrodynamic properties, as well as the retention characteristics in RP-LC of small molecules (alkylbenzenes) and of proteins under gradient elution conditions were studied. The RP selectivity depends on the type of alkyl chain in methacrylate monomer; however, there was no direct correlation between the size of the monomer molecule and methylene or aromatic selectivity of the monlithic column. The lowest selectivity was found for column based on lauryl methacrylate monomer. On the other hand, butyl methacrylate column shows high phenyl selektivity and the column with stearyl methacrylate possesses the highest methylene selectivity for small molecules. The polarity of (poly)methacrylate monolithic capillary columns was varied by using alkylmethacrylate monomers with butyl, cyclohexyl, 2-ethylhexyl, lauryl, and stearyl functional groups in the polymerization mixture. The hydrodynamic properties, as well as the retention characteristics in RP-LC of small molecules (alkylbenzenes) and of proteins under gradient elution conditions were studied. The RP selectivity depends on the type of alkyl chain in methacrylate monomer; however, there was no direct correlation between the size of the monomer molecule and methylene or aromatic selectivity of the monlithic column. The lowest selectivity was found for column based on lauryl methacrylate monomer. On the other hand, butyl methacrylate column shows high phenyl selektivity and the column with stearyl methacrylate possesses the highest methylene selectivity for small molecules.
dcterms:title
Effects of functional monomers on retention behavior of small and large molecules in monolithic capillary columns at isocratic and gradient conditions Effects of functional monomers on retention behavior of small and large molecules in monolithic capillary columns at isocratic and gradient conditions
skos:prefLabel
Effects of functional monomers on retention behavior of small and large molecules in monolithic capillary columns at isocratic and gradient conditions Effects of functional monomers on retention behavior of small and large molecules in monolithic capillary columns at isocratic and gradient conditions
skos:notation
RIV/00216275:25310/11:39892629!RIV12-GA0-25310___
n7:predkladatel
n8:orjk%3A25310
n3:aktivita
n10:P n10:Z
n3:aktivity
P(GA203/07/0641), Z(MSM0021627502)
n3:cisloPeriodika
16-17
n3:dodaniDat
n13:2012
n3:domaciTvurceVysledku
n18:6490255 n18:4487877
n3:druhVysledku
n12:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n20:predkladatel
n3:idSjednocenehoVysledku
196634
n3:idVysledku
RIV/00216275:25310/11:39892629
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Polymethacrylate; Polarity; Functional monomers; Efficiency
n3:klicoveSlovo
n9:Functional%20monomers n9:Efficiency n9:Polymethacrylate n9:Polarity
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[FFECE7E02DD3]
n3:nazevZdroje
Journal of Separation Science
n3:obor
n4:CB
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
3
n3:projekt
n16:GA203%2F07%2F0641
n3:rokUplatneniVysledku
n13:2011
n3:svazekPeriodika
34
n3:tvurceVysledku
Urban, Jiří Jandera, Pavel Langmaier, Pavel
n3:wos
000295189400012
n3:zamer
n11:MSM0021627502
s:issn
1615-9306
s:numberOfPages
9
n14:doi
10.1002/jssc.201100174
n21:organizacniJednotka
25310