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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F10%3A39882940%21RIV11-GA0-25310___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Reaction of vanadocene dichlorides (Cp2VCl2 and (C5H4Me)2VCl2) with amino acids containing secondary amino groups gives three types of complexes: a) compounds with N,O-bonded amino acid, b) O-bonded amino acids and c) O,O-bonded amino acid. The complexes with N,O-bonded amino acid and O-bonded amino acids were observed in the case of L-proline and N-methylglycine (NMG). Reactions with N-phenylglycine (NPG) give O,O-chelates as the sole products. All three types of the complexes were characterized by spectroscopic methods. Structures of [(C5H4Me)2V(O-Pro)][BPh4], [Cp2V(O-Pro)2][PF6]2, [Cp2V(N,O-NMG)][BPh4], [(C5H4Me)2V(N,O-NMG)][BPh4], [Cp2V(O-NMG)2][Cl]2, [(C5H4Me)2V(O-NMG)2][Cl]2 and [(C5H4Me)2V(O,O-NPG)][BPh4] were determined by X-ray crystallography. Reaction of vanadocene dichlorides (Cp2VCl2 and (C5H4Me)2VCl2) with amino acids containing secondary amino groups gives three types of complexes: a) compounds with N,O-bonded amino acid, b) O-bonded amino acids and c) O,O-bonded amino acid. The complexes with N,O-bonded amino acid and O-bonded amino acids were observed in the case of L-proline and N-methylglycine (NMG). Reactions with N-phenylglycine (NPG) give O,O-chelates as the sole products. All three types of the complexes were characterized by spectroscopic methods. Structures of [(C5H4Me)2V(O-Pro)][BPh4], [Cp2V(O-Pro)2][PF6]2, [Cp2V(N,O-NMG)][BPh4], [(C5H4Me)2V(N,O-NMG)][BPh4], [Cp2V(O-NMG)2][Cl]2, [(C5H4Me)2V(O-NMG)2][Cl]2 and [(C5H4Me)2V(O,O-NPG)][BPh4] were determined by X-ray crystallography.
dcterms:title
Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety.
skos:prefLabel
Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety. Vanadocene complexes of amino acids containing secondary amino group: The first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety.
skos:notation
RIV/00216275:25310/10:39882940!RIV11-GA0-25310___
n3:aktivita
n6:Z n6:P
n3:aktivity
P(GA203/09/0460), Z(MSM0021627501)
n3:cisloPeriodika
9
n3:dodaniDat
n9:2011
n3:domaciTvurceVysledku
n13:6665977 n13:7774214 n13:5107962
n3:druhVysledku
n10:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
295244
n3:idVysledku
RIV/00216275:25310/10:39882940
n3:jazykVysledku
n11:eng
n3:klicovaSlova
EPR; X-ray; amino acids; vanadocene complexes
n3:klicoveSlovo
n16:vanadocene%20complexes n16:amino%20acids n16:EPR n16:X-ray
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[6CB3FA93E2FC]
n3:nazevZdroje
Journal of Inorganic Biochemistry
n3:obor
n15:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
4
n3:projekt
n14:GA203%2F09%2F0460
n3:rokUplatneniVysledku
n9:2010
n3:svazekPeriodika
104
n3:tvurceVysledku
Vinklárek, Jaromír Růžička, Aleš Honzíček, Jan Dědourková, Tereza
n3:wos
000280679200006
n3:zamer
n19:MSM0021627501
s:issn
0162-0134
s:numberOfPages
8
n4:organizacniJednotka
25310