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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F09%3A00008582%21RIV10-MSM-25310___
rdf:type
n10:Vysledek skos:Concept
dcterms:description
Using the 15N NMR chemical shifts of nitrogen atoms in nitramino groups of bicyclo HMX or BCHMX and additional 10 nitramines,we have assessed its reactivity in detonation,under the influence of impact,and by action of electric spark.It is stated that the thermal stability of BCHMX is higher than that of RDX.The longest N-N bond in the BCHMX molecule (1.412(4) Å) is the cause of its higher impact reactivity,which is at the level of that of PETN. In the experimentally determined detonation velocity,BCMX can be slightly better as RDX. From the standpoint of friction sensitivity,BCHMX is close to HMX. Attention was also focused upon the solubility-temperature dependence of BCHMX in acetone,acetonitrile,ethyl acetate,dimethyl sulfoxide,tetrahydrofurane,and nitromethane.X-Ray crystallographic study of BCHMX (C4H6N8O8, Mr = 294.17),has been carried at the temperature of 150 K.There were found in the BCHMX molecular crystal more short contacts in the new structure making extensive supramolecular architec Using the 15N NMR chemical shifts of nitrogen atoms in nitramino groups of bicyclo HMX or BCHMX and additional 10 nitramines,we have assessed its reactivity in detonation,under the influence of impact,and by action of electric spark.It is stated that the thermal stability of BCHMX is higher than that of RDX.The longest N-N bond in the BCHMX molecule (1.412(4) Å) is the cause of its higher impact reactivity,which is at the level of that of PETN. In the experimentally determined detonation velocity,BCMX can be slightly better as RDX. From the standpoint of friction sensitivity,BCHMX is close to HMX. Attention was also focused upon the solubility-temperature dependence of BCHMX in acetone,acetonitrile,ethyl acetate,dimethyl sulfoxide,tetrahydrofurane,and nitromethane.X-Ray crystallographic study of BCHMX (C4H6N8O8, Mr = 294.17),has been carried at the temperature of 150 K.There were found in the BCHMX molecular crystal more short contacts in the new structure making extensive supramolecular architec
dcterms:title
cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity
skos:prefLabel
cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole (BCHMX), its properties and initiation reactivity
skos:notation
RIV/00216275:25310/09:00008582!RIV10-MSM-25310___
n3:aktivita
n16:Z
n3:aktivity
Z(MSM0021627501)
n3:cisloPeriodika
2-3
n3:dodaniDat
n11:2010
n3:domaciTvurceVysledku
n4:4046145 n4:3155986 n4:6919936 n4:5107962 n4:3859908
n3:druhVysledku
n7:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
307183
n3:idVysledku
RIV/00216275:25310/09:00008582
n3:jazykVysledku
n8:eng
n3:klicovaSlova
cis-1,3,4,6-Tetranitrooctahydroimidazo-[4,5-d]imidazole; detonation; initiation; sensitivity; solubility
n3:klicoveSlovo
n13:initiation n13:cis-1 n13:sensitivity n13:3 n13:4 n13:6-Tetranitrooctahydroimidazo-%5B4 n13:detonation n13:5-d%5Dimidazole n13:solubility
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[3CF0F1E2E080]
n3:nazevZdroje
Journal of Hazardous Materials
n3:obor
n17:CC
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n11:2009
n3:svazekPeriodika
164
n3:tvurceVysledku
Zeman, Svatopluk KLASOVITÝ, Dušan Jungová, Marcela Růžička, Aleš Roháč, Michal
n3:zamer
n6:MSM0021627501
s:issn
0304-3894
s:numberOfPages
8
n9:organizacniJednotka
25310