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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F08%3A00008587%21RIV10-MSM-25310___
rdf:type
n15:Vysledek skos:Concept
dcterms:description
An ESZ KTTV instrument of a new,relatively simple construction has been applied to determination of electric spark sensitivity of 29 polynitro arenes,expressed as spark energy,EES,required for 50-percent initiation probability.The thermal stability thresholds,Tmax,were calculated from the published Arrhenius parameters of monomolecular thermal decomposition of the studied compounds,predominantly obtained under the conditions of the Russian manometric method. Relationship has been found between the ln EES values and threshold Tmax values.In the sense of this relationship,the compounds studied fall into several sub-groups.The reason of the said diversification lies in the decomposition reaction rate at the temperature of onset of their thermal decomposition.It has been found that in each sub-group increasing thermal stability of polynitro arenes is accompanied by increasing electric spark sensitivity of these substances. An ESZ KTTV instrument of a new,relatively simple construction has been applied to determination of electric spark sensitivity of 29 polynitro arenes,expressed as spark energy,EES,required for 50-percent initiation probability.The thermal stability thresholds,Tmax,were calculated from the published Arrhenius parameters of monomolecular thermal decomposition of the studied compounds,predominantly obtained under the conditions of the Russian manometric method. Relationship has been found between the ln EES values and threshold Tmax values.In the sense of this relationship,the compounds studied fall into several sub-groups.The reason of the said diversification lies in the decomposition reaction rate at the temperature of onset of their thermal decomposition.It has been found that in each sub-group increasing thermal stability of polynitro arenes is accompanied by increasing electric spark sensitivity of these substances.
dcterms:title
A New Aspect of Relationships between Electric Spark Sensitivity and Thermal Stability of Some Polynitro Arenes A New Aspect of Relationships between Electric Spark Sensitivity and Thermal Stability of Some Polynitro Arenes
skos:prefLabel
A New Aspect of Relationships between Electric Spark Sensitivity and Thermal Stability of Some Polynitro Arenes A New Aspect of Relationships between Electric Spark Sensitivity and Thermal Stability of Some Polynitro Arenes
skos:notation
RIV/00216275:25310/08:00008587!RIV10-MSM-25310___
n3:aktivita
n14:Z
n3:aktivity
Z(MSM0021627501)
n3:cisloPeriodika
6
n3:dodaniDat
n8:2010
n3:domaciTvurceVysledku
n6:3859908
n3:druhVysledku
n17:J
n3:duvernostUdaju
n4:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
354284
n3:idVysledku
RIV/00216275:25310/08:00008587
n3:jazykVysledku
n18:eng
n3:klicovaSlova
electric spark sensitivity; explosives; thermal stability; polynitro arenes
n3:klicoveSlovo
n9:electric%20spark%20sensitivity n9:thermal%20stability n9:explosives n9:polynitro%20arenes
n3:kodStatuVydavatele
CN - Čínská lidová republika
n3:kontrolniKodProRIV
[92872500CE29]
n3:nazevZdroje
HanNeng CaiLiao (Chinese Journal of Energetic Materials)
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
1
n3:rokUplatneniVysledku
n8:2008
n3:svazekPeriodika
16
n3:tvurceVysledku
Zeman, Svatopluk
n3:zamer
n5:MSM0021627501
s:issn
1006-9941
s:numberOfPages
7
n11:organizacniJednotka
25310