This HTML5 document contains 52 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n13http://localhost/temp/predkladatel/
n11http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n8http://linked.opendata.cz/resource/domain/vavai/projekt/
n17http://linked.opendata.cz/ontology/domain/vavai/
n16http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F00216275%3A25310%2F08%3A00007602%21RIV09-GA0-25310___/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n4http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n14http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n9http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n6http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n18http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n5http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n15http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F08%3A00007602%21RIV09-GA0-25310___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Carbon monoxide adsorption on the zeolites Na-ZSM-5 and K-ZSM-5 was investigated by combining variable-temperature FTIR spectroscopy with calculations performed at the periodic DFT level. On the basis of a very good agreement between experimental and calculated frequencies and adsorption enthalpies, it is shown that the IR absorption band appearing in the intermediate frequency range for adsorbed CO (2155 and 2150 cm-1 for Na-ZSM-5 and K-ZSM-5, respectively) is due to the formation of linearly bridged CO adsorption complexes on dual-cation sites. Adsorpce CO na Na-ZSM-5 a K-ZSM-5 zeolitech byla studována kombinací IČ spektroskopie za různých teplot a výpočtů na periodické DFT úrovni. Na základě velmi dobré shody experimentu a teorie bylo prokázáno, že IČ pás na vlnočtech 2155 a 2150 cm-1 je způsoben vznikem lineárních můstkových komplexů adsorbovaného CO na tzv. duálních kationtových centrech. Carbon monoxide adsorption on the zeolites Na-ZSM-5 and K-ZSM-5 was investigated by combining variable-temperature FTIR spectroscopy with calculations performed at the periodic DFT level. On the basis of a very good agreement between experimental and calculated frequencies and adsorption enthalpies, it is shown that the IR absorption band appearing in the intermediate frequency range for adsorbed CO (2155 and 2150 cm-1 for Na-ZSM-5 and K-ZSM-5, respectively) is due to the formation of linearly bridged CO adsorption complexes on dual-cation sites.
dcterms:title
Computational and FTIR Spectroscopic Studies on CO Adsorption on the Zeolites Na-ZSM-5 and K-ZSM-5: Evidence of Dual-cation Sites Computational and FTIR Spectroscopic Studies on CO Adsorption on the Zeolites Na-ZSM-5 and K-ZSM-5: Evidence of Dual-cation Sites Výpočetní a FTIR spektroskopická studie adsorpce CO na Na-ZSM-5 a K-ZSM-5: důkaz duálních kationtových center
skos:prefLabel
Computational and FTIR Spectroscopic Studies on CO Adsorption on the Zeolites Na-ZSM-5 and K-ZSM-5: Evidence of Dual-cation Sites Výpočetní a FTIR spektroskopická studie adsorpce CO na Na-ZSM-5 a K-ZSM-5: důkaz duálních kationtových center Computational and FTIR Spectroscopic Studies on CO Adsorption on the Zeolites Na-ZSM-5 and K-ZSM-5: Evidence of Dual-cation Sites
skos:notation
RIV/00216275:25310/08:00007602!RIV09-GA0-25310___
n3:aktivita
n9:S n9:P
n3:aktivity
P(GA203/06/0324), P(LC512), S
n3:cisloPeriodika
12
n3:dodaniDat
n15:2009
n3:domaciTvurceVysledku
n11:7420900 n11:9333312 n11:1747681
n3:druhVysledku
n5:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
360861
n3:idVysledku
RIV/00216275:25310/08:00007602
n3:jazykVysledku
n6:eng
n3:klicovaSlova
zeolite; CO; dual sites; adsorption; DFT level
n3:klicoveSlovo
n4:adsorption n4:CO n4:dual%20sites n4:zeolite n4:DFT%20level
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[8DE606DFC626]
n3:nazevZdroje
Journal of Physical Chemistry Part C: Nanomaterials and Interfaces
n3:obor
n18:CF
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
7
n3:projekt
n8:GA203%2F06%2F0324 n8:LC512
n3:rokUplatneniVysledku
n15:2008
n3:svazekPeriodika
112
n3:tvurceVysledku
Bulánek, Roman Frolich, Karel Nachtigall, Petr Pulido, A. Areán, C. Otero Bibiloni, G. Fiol Delgado, M. Rodríguez
s:issn
1932-7447
s:numberOfPages
9
n13:organizacniJednotka
25310