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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F07%3A00006086%21RIV08-MSM-25310___
rdf:type
n10:Vysledek skos:Concept
dcterms:description
EPR study of vanadocene complexes (C5H5)2V(CN)2 and (CH3C5H4)2V(CN)2 was done. Such compounds show strong super-hyperfine coupling (|aiso(13C)| ~ 11.85 x 10-4 cm-1) when 13C labeled cyanide was used for their preparation. Super-hyperfine splitting was observed in isotropic spectra of solution samples as well as in anisotropic spectra of frozen solutions. Such study was suplemented with structural characterization of parent compounds. Molecular structure of complex (CH3C5H4)2V(CN)2 was determined by single crystal X-ray diffraction analysis. Both compounds were characterized by infrared and Raman spectra. EPR study of vanadocene complexes (C5H5)2V(CN)2 and (CH3C5H4)2V(CN)2 was done. Such compounds show strong super-hyperfine coupling (|aiso(13C)| ~ 11.85 x 10-4 cm-1) when 13C labeled cyanide was used for their preparation. Super-hyperfine splitting was observed in isotropic spectra of solution samples as well as in anisotropic spectra of frozen solutions. Such study was suplemented with structural characterization of parent compounds. Molecular structure of complex (CH3C5H4)2V(CN)2 was determined by single crystal X-ray diffraction analysis. Both compounds were characterized by infrared and Raman spectra. EPR study of vanadocene complexes (C5H5)2V(CN)2 and (CH3C5H4)2V(CN)2 was done. Such compounds show strong super-hyperfine coupling (|aiso(13C)| ~ 11.85 x 10-4 cm-1) when 13C labeled cyanide was used for their preparation. Super-hyperfine splitting was observed in isotropic spectra of solution samples as well as in anisotropic spectra of frozen solutions. Such study was suplemented with structural characterization of parent compounds. Molecular structure of complex (CH3C5H4)2V(CN)2 was determined by single crystal X-ray diffraction analysis. Both compounds were characterized by infrared and Raman spectra.
dcterms:title
Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands
skos:prefLabel
Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands Vanadocene(IV) dicyanide complexes: The evidence superhyperfine coupling for compounds with 13CN ligands
skos:notation
RIV/00216275:25310/07:00006086!RIV08-MSM-25310___
n3:strany
508-512
n3:aktivita
n14:Z
n3:aktivity
Z(MSM0021627501)
n3:cisloPeriodika
45
n3:dodaniDat
n8:2008
n3:domaciTvurceVysledku
n6:7774214 n6:4199693
n3:druhVysledku
n11:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
457468
n3:idVysledku
RIV/00216275:25310/07:00006086
n3:jazykVysledku
n16:eng
n3:klicovaSlova
bent metallocene; pseudohalide complexes; EPR spectroscopy; super-hyperfine coupling; X-ray structure
n3:klicoveSlovo
n7:pseudohalide%20complexes n7:X-ray%20structure n7:super-hyperfine%20coupling n7:bent%20metallocene n7:EPR%20spectroscopy
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[F52988549B9B]
n3:nazevZdroje
Magnetic Resonance in Chemistry
n3:obor
n9:CA
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
4
n3:rokUplatneniVysledku
n8:2007
n3:svazekPeriodika
45
n3:tvurceVysledku
Císařová, Ivana Vinklárek, Jaromír Černošek, Zdeněk Honzíček, Jan
n3:zamer
n17:MSM0021627501
s:issn
0749-1581
s:numberOfPages
5
n15:organizacniJednotka
25310