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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F06%3A00004344%21RIV08-MSM-25310___
rdf:type
n18:Vysledek skos:Concept
dcterms:description
The spin-coating method was used for the preparation of amorphous chalcogenide As33S67-xSex lms, where x = 0, 17, 33.5, 50 and 67 at.%. The lms were stabilized in a vacuum furnace at 70 oC for 10 hours. The compositions of the lms, established by Energy-Dispersive X-ray analysis, were similar to the composition of the glass used for the preparation of the solutions. The optical transmission measurements indicated that the optical band gap decreases with increasing Se-content in the lms. Raman spectroscopy showed the lms structure i.e. As?S bonds at 344 and 376 cm-1, S-rings at 495 cm-1 and appearance of As?Se bonds at 225 cm-1, Se chains at 254 cm-1 and S?Se bonds at 416 cm-1 with increasing Se-content. MIR transmission spectra revealed the presence of solvent residua in spin-coated lms i.e. N?H bonds at 3395?3300 cm-1, C?H bonds at 2980?2850 cm-1. Further annealing of the lms (150 oC, 0?60 min) caused decrease of N?H and C?H stretching vibration intensities. Raman spectra showed that the annea The spin-coating method was used for the preparation of amorphous chalcogenide As33S67-xSex lms, where x = 0, 17, 33.5, 50 and 67 at.%. The lms were stabilized in a vacuum furnace at 70 oC for 10 hours. The compositions of the lms, established by Energy-Dispersive X-ray analysis, were similar to the composition of the glass used for the preparation of the solutions. The optical transmission measurements indicated that the optical band gap decreases with increasing Se-content in the lms. Raman spectroscopy showed the lms structure i.e. As?S bonds at 344 and 376 cm-1, S-rings at 495 cm-1 and appearance of As?Se bonds at 225 cm-1, Se chains at 254 cm-1 and S?Se bonds at 416 cm-1 with increasing Se-content. MIR transmission spectra revealed the presence of solvent residua in spin-coated lms i.e. N?H bonds at 3395?3300 cm-1, C?H bonds at 2980?2850 cm-1. Further annealing of the lms (150 oC, 0?60 min) caused decrease of N?H and C?H stretching vibration intensities. Raman spectra showed that the annea The spin-coating method was used for the preparation of amorphous chalcogenide As33S67-xSex lms, where x = 0, 17, 33.5, 50 and 67 at.%. The lms were stabilized in a vacuum furnace at 70 oC for 10 hours. The compositions of the lms, established by Energy-Dispersive X-ray analysis, were similar to the composition of the glass used for the preparation of the solutions. The optical transmission measurements indicated that the optical band gap decreases with increasing Se-content in the lms. Raman spectroscopy showed the lms structure i.e. As?S bonds at 344 and 376 cm-1, S-rings at 495 cm-1 and appearance of As?Se bonds at 225 cm-1, Se chains at 254 cm-1 and S?Se bonds at 416 cm-1 with increasing Se-content. MIR transmission spectra revealed the presence of solvent residua in spin-coated lms i.e. N?H bonds at 3395?3300 cm-1, C?H bonds at 2980?2850 cm-1. Further annealing of the lms (150 oC, 0?60 min) caused decrease of N?H and C?H stretching vibration intensities. Raman spectra showed that the annea
dcterms:title
Spin-coated As33S67-xSex thin lms: the effect of annealing Tenké vrstvy systému As33S67-xSex deponované metodou spin-coating: vliv temperace Spin-coated As33S67-xSex thin lms: the effect of annealing
skos:prefLabel
Spin-coated As33S67-xSex thin lms: the effect of annealing Spin-coated As33S67-xSex thin lms: the effect of annealing Tenké vrstvy systému As33S67-xSex deponované metodou spin-coating: vliv temperace
skos:notation
RIV/00216275:25310/06:00004344!RIV08-MSM-25310___
n3:strany
1563-1566
n3:aktivita
n13:Z n13:P
n3:aktivity
P(GA203/05/0524), P(GA203/06/1368), P(LC523), Z(MSM0021627501)
n3:cisloPeriodika
9-20
n3:dodaniDat
n4:2008
n3:domaciTvurceVysledku
n14:3110869 n14:1620290 n14:6649440 n14:1580388 n14:3359301
n3:druhVysledku
n15:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
500837
n3:idVysledku
RIV/00216275:25310/06:00004344
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Spin-coating; Chalcogenides; Optical spectroscopy; FTIR measurements; Raman spectroscopy
n3:klicoveSlovo
n7:Chalcogenides n7:Optical%20spectroscopy n7:FTIR%20measurements n7:Spin-coating n7:Raman%20spectroscopy
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[D2E512CBB83E]
n3:nazevZdroje
Journal of Non-Crystalline Solids
n3:obor
n17:CA
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:projekt
n6:LC523 n6:GA203%2F05%2F0524 n6:GA203%2F06%2F1368
n3:rokUplatneniVysledku
n4:2006
n3:svazekPeriodika
352
n3:tvurceVysledku
Wágner, Tomáš Vlček, Miroslav Vlček, Milan Kohoutek, Tomáš Frumar, Miloslav
n3:zamer
n11:MSM0021627501
s:issn
0022-3093
s:numberOfPages
4
n16:organizacniJednotka
25310