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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F04%3A00003527%21RIV08-MSM-25310___
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Půlvlnný potenciál dvaceti čtyři polynitro arenes byl stanovený ve vodných prostředích pufrovaných na pH 7, pro dvě koncentrace. Nalezené logické vztahy mezi těmito potenciály a čtverci detonačních rychlosti jsou jedním z forem modifikované Evans?Polanyi?Semenovovy rovnice pro energetické materiály. Silná závislost hodnoty potenciálů na podmínkách a způsobu polarografických měření značně omezujr použití polarografie ve studiu mikro-mechanismu uvedení organických materiálů The half-wave potentials, E1/2, of twenty four polynitro arenes have been determined in aqueous medium buffered at pH 7, the final concentrations of their solutions being 0.5x10?4 M and 0.5x10?5 M. The found logical relationships between the E1/2 values and squares of detonation velocity are of the type of the modified Evans?Polanyi?Semenov equation for energetic materials. It has been stated that the strong dependence of E1/2 values on the conditions and way of realisation of the polarographic measurements considerably restrict the application of this method to studies of micro-mechanism of initiation of organic energetic materials. The half-wave potentials, E1/2, of twenty four polynitro arenes have been determined in aqueous medium buffered at pH 7, the final concentrations of their solutions being 0.5x10?4 M and 0.5x10?5 M. The found logical relationships between the E1/2 values and squares of detonation velocity are of the type of the modified Evans?Polanyi?Semenov equation for energetic materials. It has been stated that the strong dependence of E1/2 values on the conditions and way of realisation of the polarographic measurements considerably restrict the application of this method to studies of micro-mechanism of initiation of organic energetic materials.
dcterms:title
Polarografie ve studiu chenického mikro-mechanizmu iniciace polynitroarenů Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes
skos:prefLabel
Polarografie ve studiu chenického mikro-mechanizmu iniciace polynitroarenů Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes Polarography in the Study of Chemical Micro-Mechanism of Initiation of Polynitro Arenes
skos:notation
RIV/00216275:25310/04:00003527!RIV08-MSM-25310___
n3:strany
171-179
n3:aktivita
n5:S
n3:aktivity
S
n3:cisloPeriodika
22
n3:dodaniDat
n7:2008
n3:domaciTvurceVysledku
n15:3859908
n3:druhVysledku
n10:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
580082
n3:idVysledku
RIV/00216275:25310/04:00003527
n3:jazykVysledku
n11:eng
n3:klicovaSlova
Polarography; Chemical Micro-Mechanism of Initiation; Polynitro Arenes
n3:klicoveSlovo
n13:Polarography n13:Chemical%20Micro-Mechanism%20of%20Initiation n13:Polynitro%20Arenes
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[A570F14CB677]
n3:nazevZdroje
Journal of Energetic Materials
n3:obor
n17:CC
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
2
n3:rokUplatneniVysledku
n7:2004
n3:svazekPeriodika
N
n3:tvurceVysledku
Zemanová, Eva Zeman, Svatopluk
s:issn
0737-0652
s:numberOfPages
9
n6:organizacniJednotka
25310