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Statements

Subject Item
n2:RIV%2F00216275%3A25310%2F00%3A00003867%21RIV06-MSM-25310___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
The influence of modifications of the mercuric oxide on the voltammetric properties of mercury film carbon paste electrodes was studied. The mercury film was formed electrochemically from the bulk red or yellow mercuric oxide-modified carbon paste electrodes. Differential pulse anodic stripping voltammetry and optical microscopy in polarised light were used to characterise the properties of the mercury films. The results were compared with those obtained using the conventional preparation of mercury-plated carbon paste electrodes when the mercury film is deposited on the surface of the electrode by reduction of Hg(II) ions in solution utilising a sufficient negative potential. It was shown that the mercury film formed from the yellow modification of the mercuric oxide provides better voltammetric characteristics than the red one owing to the high distribution of its small particles, i.e. the mercury droplets after electrochemical treatment. Such a mercury film has similar properties to those of a merc The influence of modifications of the mercuric oxide on the voltammetric properties of mercury film carbon paste electrodes was studied. The mercury film was formed electrochemically from the bulk red or yellow mercuric oxide-modified carbon paste electrodes. Differential pulse anodic stripping voltammetry and optical microscopy in polarised light were used to characterise the properties of the mercury films. The results were compared with those obtained using the conventional preparation of mercury-plated carbon paste electrodes when the mercury film is deposited on the surface of the electrode by reduction of Hg(II) ions in solution utilising a sufficient negative potential. It was shown that the mercury film formed from the yellow modification of the mercuric oxide provides better voltammetric characteristics than the red one owing to the high distribution of its small particles, i.e. the mercury droplets after electrochemical treatment. Such a mercury film has similar properties to those of a merc Vliv modifikace oxidu rtuťnatého na vlastnosti rtuťového filmu na uhlíkových pastových elektrodách s oxidem rtuťnatým
dcterms:title
Vliv modifikace oxidu rtuťnatého na vlastnosti rtuťového filmu na uhlíkových pastových elektrodách s oxidem rtuťnatým Effect of the modification of mercuric oxide on the properties of mercury films at HgO-modified carbon paste electrodes Effect of the modification of mercuric oxide on the properties of mercury films at HgO-modified carbon paste electrodes
skos:prefLabel
Effect of the modification of mercuric oxide on the properties of mercury films at HgO-modified carbon paste electrodes Effect of the modification of mercuric oxide on the properties of mercury films at HgO-modified carbon paste electrodes Vliv modifikace oxidu rtuťnatého na vlastnosti rtuťového filmu na uhlíkových pastových elektrodách s oxidem rtuťnatým
skos:notation
RIV/00216275:25310/00:00003867!RIV06-MSM-25310___
n3:strany
348-352
n3:aktivita
n8:P
n3:aktivity
P(GA203/99/0044), P(OE37/1)
n3:cisloPeriodika
6
n3:dodaniDat
n10:2006
n3:domaciTvurceVysledku
n15:6143083 n15:9465421
n3:druhVysledku
n18:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
709768
n3:idVysledku
RIV/00216275:25310/00:00003867
n3:jazykVysledku
n14:eng
n3:klicovaSlova
mercuric oxide; mercury film; modified carbon paste electrode; anodic stripping voltammetry; optical microscopy
n3:klicoveSlovo
n4:optical%20microscopy n4:modified%20carbon%20paste%20electrode n4:mercuric%20oxide n4:mercury%20film n4:anodic%20stripping%20voltammetry
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[EACBABB2FFCA]
n3:nazevZdroje
Journal of Solid State Electrochemistry
n3:obor
n7:DJ
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
3
n3:projekt
n9:OE37%2F1 n9:GA203%2F99%2F0044
n3:rokUplatneniVysledku
n10:2000
n3:tvurceVysledku
Bobrowski, A. Vytřas, Karel Metelka, Radovan
s:issn
1432-8488
s:numberOfPages
5
n13:organizacniJednotka
25310