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Statements

Subject Item
n2:RIV%2F00216224%3A14740%2F14%3A00076814%21RIV15-MSM-14740___
rdf:type
n9:Vysledek skos:Concept
rdfs:seeAlso
http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc01992j#!divAbstract
dcterms:description
High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules. High-resolution FT-IR spectroscopy combined with quantum chemical calculations was used to study the chemistry of OCS-disproportionation over the reduced surface of isotopically labelled, nanocrystalline TiO2. Analysis of the isotopic composition of the product gases has revealed that the reaction involves solely OCS molecules fromthe gas-phase. Using quantumchemical calculations we propose a plausible mechanistic scenario, in which two reduced Ti3+ centres mediate the reaction of the adsorbed OCS molecules.
dcterms:title
Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface
skos:prefLabel
Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface Room temperature spontaneous conversion of OCS to CO2 on the anatase TiO2 surface
skos:notation
RIV/00216224:14740/14:00076814!RIV15-MSM-14740___
n3:aktivita
n14:P n14:I
n3:aktivity
I, P(LD13060), P(LD14115)
n3:cisloPeriodika
57
n3:dodaniDat
n18:2015
n3:domaciTvurceVysledku
n4:5279909 n4:3223779
n3:druhVysledku
n15:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
43274
n3:idVysledku
RIV/00216224:14740/14:00076814
n3:jazykVysledku
n13:eng
n3:klicovaSlova
TITANIUM-DIOXIDE; OXYGEN-EXCHANGE; CARBON-MONOXIDE; HYDROCARBONS; CHEMISTRY; TIO2(101); OXIDATION; ISOTOPE; METAL; FTIR
n3:klicoveSlovo
n7:OXIDATION n7:METAL n7:CHEMISTRY n7:TIO2%28101%29 n7:TITANIUM-DIOXIDE n7:ISOTOPE n7:OXYGEN-EXCHANGE n7:HYDROCARBONS n7:FTIR n7:CARBON-MONOXIDE
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[F3F52B64A2C8]
n3:nazevZdroje
Chemical Communications
n3:obor
n5:CF
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
6
n3:projekt
n6:LD13060 n6:LD14115
n3:rokUplatneniVysledku
n18:2014
n3:svazekPeriodika
50
n3:tvurceVysledku
Zukalová, Markéta Kavan, Ladislav Šponer, Jiří Šponerová, Judit Ferus, Martin Civiš, Svatopluk
n3:wos
000338234000038
s:issn
1359-7345
s:numberOfPages
4
n12:doi
10.1039/c4cc01992j
n20:organizacniJednotka
14740