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Statements

Subject Item
n2:RIV%2F00216224%3A14740%2F14%3A00074841%21RIV15-MSM-14740___
rdf:type
skos:Concept n17:Vysledek
rdfs:seeAlso
http://yadda.icm.edu.pl/yadda/element/bwmeta1.element.elsevier-10d0e0df-971c-36d4-9d50-3d8102c58420
dcterms:description
The Cu-Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu-Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu-Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy. The Cu-Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu-Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu-Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy.
dcterms:title
Cu–Ni nanoalloy phase diagram – Prediction and experiment Cu–Ni nanoalloy phase diagram – Prediction and experiment
skos:prefLabel
Cu–Ni nanoalloy phase diagram – Prediction and experiment Cu–Ni nanoalloy phase diagram – Prediction and experiment
skos:notation
RIV/00216224:14740/14:00074841!RIV15-MSM-14740___
n3:aktivita
n19:P n19:I
n3:aktivity
I, P(ED1.1.00/02.0068), P(LD11046)
n3:cisloPeriodika
June
n3:dodaniDat
n15:2015
n3:domaciTvurceVysledku
n9:6119409 n9:7592132 n9:9678093 n9:2274329 n9:1631055 n9:2794918 n9:8673152
n3:druhVysledku
n5:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
9404
n3:idVysledku
RIV/00216224:14740/14:00074841
n3:jazykVysledku
n4:eng
n3:klicovaSlova
nanoalloy; phase diagram; thermodynamic modeling; characterization; surface energy
n3:klicoveSlovo
n8:phase%20diagram n8:thermodynamic%20modeling n8:characterization n8:nanoalloy n8:surface%20energy
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[9C7758888C76]
n3:nazevZdroje
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
n3:obor
n10:CF
n3:pocetDomacichTvurcuVysledku
7
n3:pocetTvurcuVysledku
9
n3:projekt
n12:ED1.1.00%2F02.0068 n12:LD11046
n3:rokUplatneniVysledku
n15:2014
n3:svazekPeriodika
45
n3:tvurceVysledku
Zobač, Ondřej Buršík, Jiří Lee, Joonho Pinkas, Jiří Sopoušek, Jiří Brož, Pavel Škoda, David Stýskalík, Aleš Vřešťál, Jan
n3:wos
000337880600004
s:issn
0364-5916
s:numberOfPages
7
n6:doi
10.1016/j.calphad.2013.11.004
n13:organizacniJednotka
14740