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Statements

Subject Item
n2:RIV%2F00216224%3A14740%2F13%3A00066398%21RIV14-MSM-14740___
rdf:type
n3:Vysledek skos:Concept
rdfs:seeAlso
http://www.sciencedirect.com/science/article/pii/S0277538713004270#
dcterms:description
The kinetic inertness of copper(II) complexes with cyclen-based ligands having three (H(3)do3a) or four (H(4)dota) acetic acid arms and those with three acetic acid and one phosphonic (H(5)do3ap), phosphinic (H(5)do(3)ap(PrA) , H(4)do3ap(ABn)) acid or methylpyridine-N-oxide (H(3)do3a-pyNox) pendant arms has been studied. The proton-assisted decomplexation reaction was studied under a wide range of conditions to fully assess the parameters influencing the reaction (temperature range 25-60 degrees C, proton concentration range 0.05-5 M and presence of perchlorate or nitrate anions). The empirical rate law k(d,obs) = k(0) + k(H) x [H+], involving solvolytic and proton-assisted dissociation pathways, shows that the complexes can be divided into two groups according to their kinetic behavior. The kinetic inertness of copper(II) complexes with cyclen-based ligands having three (H(3)do3a) or four (H(4)dota) acetic acid arms and those with three acetic acid and one phosphonic (H(5)do3ap), phosphinic (H(5)do(3)ap(PrA) , H(4)do3ap(ABn)) acid or methylpyridine-N-oxide (H(3)do3a-pyNox) pendant arms has been studied. The proton-assisted decomplexation reaction was studied under a wide range of conditions to fully assess the parameters influencing the reaction (temperature range 25-60 degrees C, proton concentration range 0.05-5 M and presence of perchlorate or nitrate anions). The empirical rate law k(d,obs) = k(0) + k(H) x [H+], involving solvolytic and proton-assisted dissociation pathways, shows that the complexes can be divided into two groups according to their kinetic behavior.
dcterms:title
Dissociation kinetics study of copper(II) complexes of DO3A, DOTA and its monosubstituted derivatives Dissociation kinetics study of copper(II) complexes of DO3A, DOTA and its monosubstituted derivatives
skos:prefLabel
Dissociation kinetics study of copper(II) complexes of DO3A, DOTA and its monosubstituted derivatives Dissociation kinetics study of copper(II) complexes of DO3A, DOTA and its monosubstituted derivatives
skos:notation
RIV/00216224:14740/13:00066398!RIV14-MSM-14740___
n3:predkladatel
n4:orjk%3A14740
n5:aktivita
n10:I n10:P n10:Z
n5:aktivity
I, P(ED1.1.00/02.0068), P(GA13-08336S), P(ME09065), Z(MSM0021620857)
n5:cisloPeriodika
Sep
n5:dodaniDat
n9:2014
n5:domaciTvurceVysledku
n8:6897541 n8:4161459 n8:5135001 n8:9007563
n5:druhVysledku
n15:J
n5:duvernostUdaju
n18:S
n5:entitaPredkladatele
n16:predkladatel
n5:idSjednocenehoVysledku
69929
n5:idVysledku
RIV/00216224:14740/13:00066398
n5:jazykVysledku
n6:eng
n5:klicovaSlova
Macrocyclic ligands; Cyclen derivatives; Phosphonate complexes; Phosphinate complexes; Pyridine-N-oxide complexes; Copper complexes; Dissociation kinetics; Rate constants; Radiopharmaceuticals
n5:klicoveSlovo
n13:Rate%20constants n13:Macrocyclic%20ligands n13:Radiopharmaceuticals n13:Pyridine-N-oxide%20complexes n13:Phosphonate%20complexes n13:Copper%20complexes n13:Cyclen%20derivatives n13:Dissociation%20kinetics n13:Phosphinate%20complexes
n5:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n5:kontrolniKodProRIV
[AF1031169340]
n5:nazevZdroje
Polyhedron
n5:obor
n21:CA
n5:pocetDomacichTvurcuVysledku
4
n5:pocetTvurcuVysledku
6
n5:projekt
n11:GA13-08336S n11:ED1.1.00%2F02.0068 n11:ME09065
n5:rokUplatneniVysledku
n9:2013
n5:svazekPeriodika
61
n5:tvurceVysledku
Voráčová, Ivona Lubal, Přemysl Střelcová, Zora Hermann, Petr Vaněk, Jakub Pasulka, Josef
n5:wos
000322938100014
n5:zamer
n17:MSM0021620857
s:issn
0277-5387
s:numberOfPages
6
n12:doi
10.1016/j.poly.2013.05.042
n19:organizacniJednotka
14740