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Statements

Subject Item
n2:RIV%2F00216224%3A14740%2F12%3A00079730%21RIV15-MSM-14740___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
A series of distorted square planar palladium(II) complexes with dithiocarbamic acids of general formula [Pd(L)(2)], where L = 4-methylpiperazine-l-carbodithioic acid anion, morpholine-4-carbodithioic acid anion or 4-benzylpiperidine-l-carbodithioic acid anion for complexes 1a, 1b and 1c, respectively, have been synthesized. The complexes were characterized by physicochemical and spectroscopic methods; in addition, the structure of complex 1a was characterized by single crystal X-ray crystallography. The interaction of these palladium complexes with CT-DNA was investigated with the help of absorption and emission spectroscopy. The association constant K-b was deduced from the absorption spectra, while the number of binding sites and the binding constant were calculated from the fluorescence quenching data. The results suggest an intercalative interaction of the complexes with CT-DNA. A series of distorted square planar palladium(II) complexes with dithiocarbamic acids of general formula [Pd(L)(2)], where L = 4-methylpiperazine-l-carbodithioic acid anion, morpholine-4-carbodithioic acid anion or 4-benzylpiperidine-l-carbodithioic acid anion for complexes 1a, 1b and 1c, respectively, have been synthesized. The complexes were characterized by physicochemical and spectroscopic methods; in addition, the structure of complex 1a was characterized by single crystal X-ray crystallography. The interaction of these palladium complexes with CT-DNA was investigated with the help of absorption and emission spectroscopy. The association constant K-b was deduced from the absorption spectra, while the number of binding sites and the binding constant were calculated from the fluorescence quenching data. The results suggest an intercalative interaction of the complexes with CT-DNA.
dcterms:title
Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study
skos:prefLabel
Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study Palladium(II) complexes of dithiocarbamic acids: synthesis, characterization, crystal structure and DNA binding study
skos:notation
RIV/00216224:14740/12:00079730!RIV15-MSM-14740___
n3:aktivita
n8:I
n3:aktivity
I
n3:cisloPeriodika
2
n3:dodaniDat
n16:2015
n3:domaciTvurceVysledku
n9:8675058
n3:druhVysledku
n11:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
157664
n3:idVysledku
RIV/00216224:14740/12:00079730
n3:jazykVysledku
n18:eng
n3:klicovaSlova
CALF THYMUS-DNA; PYRROLIDINE DITHIOCARBAMATE; FLUORESCENCE; SPECTROSCOPY; APOPTOSIS; CU2+
n3:klicoveSlovo
n4:APOPTOSIS n4:CALF%20THYMUS-DNA n4:CU2%2B n4:FLUORESCENCE n4:SPECTROSCOPY n4:PYRROLIDINE%20DITHIOCARBAMATE
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[AAA1A0FF76DE]
n3:nazevZdroje
Transition Metal Chemistry
n3:obor
n13:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n16:2012
n3:svazekPeriodika
37
n3:tvurceVysledku
Sarkar, Sandipan Chattopadhyay, Pabitra Marek, Jaromír Mukherjee, Titas Zangrando, Ennio
n3:wos
000302376000005
s:issn
0340-4285
s:numberOfPages
7
n17:doi
10.1007/s11243-011-9569-9
n12:organizacniJednotka
14740