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Statements

Subject Item
n2:RIV%2F00216224%3A14330%2F99%3A00005899%21RIV08-MSM-14330___
rdf:type
n9:Vysledek skos:Concept
dcterms:description
The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity. The first elimination function eliminates the kinetic current ( ) and conserves the diffusion current ( ). The second elimination function eliminates kinetic and charging currents ( and ) simultaneously and conserves the diffusion current ( ). Both functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linea The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity. The first elimination function eliminates the kinetic current ( ) and conserves the diffusion current ( ). The second elimination function eliminates kinetic and charging currents ( and ) simultaneously and conserves the diffusion current ( ). Both functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linea The elimination voltammetry with linear scan (EVLS) was used to study adenine and cytosine reduction signals at the mercury electrode. In comparison with the linear scan voltammetry providing only one unresolved peak, two elimination functions provide good resolution of individual peaks and significant increase of sensitivity. The first elimination function eliminates the kinetic current ( ) and conserves the diffusion current ( ). The second elimination function eliminates kinetic and charging currents ( and ) simultaneously and conserves the diffusion current ( ). Both functions give two well resolved peaks of adenine and cytosine in a wide concentration range, while the linear sweep voltammetry gives badly resolved peaks due to the hydrogen evolution. The best resolution of peaks is observed in acetate buffer at pH 3.8 and a detection limit for both substances is 500 nM. The concentration dependence of EVLS peak heights for one substance at the constant concentration of the other substance is linea
dcterms:title
Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals
skos:prefLabel
Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals Elimination Voltammetry - Modern Electroanalytical Method for Resolution of Overlapped Voltammetric Signals
skos:notation
RIV/00216224:14330/99:00005899!RIV08-MSM-14330___
n4:strany
40
n4:aktivita
n16:Z n16:P
n4:aktivity
P(GA511/95/1279), P(GV204/97/K084), Z(MSM 143100008), Z(MSM 143100011)
n4:dodaniDat
n14:2008
n4:domaciTvurceVysledku
n13:3730832 n13:6116957 n13:3790185
n4:druhVysledku
n20:D
n4:duvernostUdaju
n12:S
n4:entitaPredkladatele
n15:predkladatel
n4:idSjednocenehoVysledku
739870
n4:idVysledku
RIV/00216224:14330/99:00005899
n4:jazykVysledku
n22:eng
n4:klicovaSlova
elimination voltammtery (EVLS); elimination of chosen currents; analytical application of EVLS; reduction processes of adenine and cytosine; transfer coefficient
n4:klicoveSlovo
n6:elimination%20of%20chosen%20currents n6:elimination%20voltammtery%20%28EVLS%29 n6:reduction%20processes%20of%20adenine%20and%20cytosine n6:analytical%20application%20of%20EVLS n6:transfer%20coefficient
n4:kontrolniKodProRIV
[CC4D24903526]
n4:mistoKonaniAkce
Seč, Czech Republic
n4:mistoVydani
Pardubice
n4:nazevZdroje
Modern Electroanalytical Methods
n4:obor
n5:CG
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
3
n4:projekt
n11:GA511%2F95%2F1279 n11:GV204%2F97%2FK084
n4:rokUplatneniVysledku
n14:1999
n4:tvurceVysledku
Friml, Jiří Trnková, Libuše Dračka, Oldřich
n4:typAkce
n21:WRD
n4:zahajeniAkce
1999-01-01+01:00
n4:zamer
n19:MSM%20143100008 n19:MSM%20143100011
s:numberOfPages
1
n17:hasPublisher
Univerzita Pardubice
n18:isbn
80-7194-212-X
n8:organizacniJednotka
14330