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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F12%3A00060137%21RIV13-MSM-14310___
rdf:type
skos:Concept n9:Vysledek
dcterms:description
The metal complexes of chlorinated and methoxylated derivatives of 6 - benzylaminopurine (6-BAP) can be used as potential antineoplastic agents. From this point of view, the knowledge of the ability of these substances to diffuse into the intracellular area is very important. This property is characterized by the diffusion coefficient. The aim of our research is to determine the diffusion coefficients D of 6-BAP and its derivatives in buffered solutions (pH 3.21) containing 10% v/v CH3OH for two ionic strengths. Using the Delahay equation involving the reduction peaks of BAP derivatives on mercury electrode we calculated D and the charge transfer coefficient alpha we obtained from the elimination functions E1 and E4. The effect of some experimental parameters on D values was monitored. The metal complexes of chlorinated and methoxylated derivatives of 6 - benzylaminopurine (6-BAP) can be used as potential antineoplastic agents. From this point of view, the knowledge of the ability of these substances to diffuse into the intracellular area is very important. This property is characterized by the diffusion coefficient. The aim of our research is to determine the diffusion coefficients D of 6-BAP and its derivatives in buffered solutions (pH 3.21) containing 10% v/v CH3OH for two ionic strengths. Using the Delahay equation involving the reduction peaks of BAP derivatives on mercury electrode we calculated D and the charge transfer coefficient alpha we obtained from the elimination functions E1 and E4. The effect of some experimental parameters on D values was monitored.
dcterms:title
Diffusion Characteristics of Chlorine and Methoxy Derivatives of 6-benzylaminopurine Studied by Voltammetric Methods Diffusion Characteristics of Chlorine and Methoxy Derivatives of 6-benzylaminopurine Studied by Voltammetric Methods
skos:prefLabel
Diffusion Characteristics of Chlorine and Methoxy Derivatives of 6-benzylaminopurine Studied by Voltammetric Methods Diffusion Characteristics of Chlorine and Methoxy Derivatives of 6-benzylaminopurine Studied by Voltammetric Methods
skos:notation
RIV/00216224:14310/12:00060137!RIV13-MSM-14310___
n9:predkladatel
n10:orjk%3A14310
n4:aktivita
n20:S
n4:aktivity
S
n4:dodaniDat
n15:2013
n4:domaciTvurceVysledku
n6:6359922 n6:3790185
n4:druhVysledku
n17:D
n4:duvernostUdaju
n5:S
n4:entitaPredkladatele
n14:predkladatel
n4:idSjednocenehoVysledku
131288
n4:idVysledku
RIV/00216224:14310/12:00060137
n4:jazykVysledku
n13:eng
n4:klicovaSlova
chlorine and methoxy derivatives; diffusion coefficient; Delahay equation; linear sweep voltammetry; elimination voltammetry with linear scan
n4:klicoveSlovo
n7:Delahay%20equation n7:chlorine%20and%20methoxy%20derivatives n7:elimination%20voltammetry%20with%20linear%20scan n7:diffusion%20coefficient n7:linear%20sweep%20voltammetry
n4:kontrolniKodProRIV
[F698FB7966C4]
n4:mistoKonaniAkce
Jetřichovice
n4:mistoVydani
Ústí nad Labem
n4:nazevZdroje
XXXII. Moderní elektrochemické metody. Sborník přednášek.
n4:obor
n16:CF
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
2
n4:rokUplatneniVysledku
n15:2012
n4:tvurceVysledku
Pilařová, Iveta Trnková, Libuše
n4:typAkce
n21:EUR
n4:zahajeniAkce
2012-01-01+01:00
s:numberOfPages
5
n19:hasPublisher
BEST Servis
n11:isbn
9788090522107
n18:organizacniJednotka
14310