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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F11%3A00052417%21RIV12-MSM-14310___
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Derivatives of adenine, known as cytokinins (CKs), are one of the five major groups of phytohormones, which support cell division, bud formation, branching of stems, and metabolism of plants. One of the most important cytokinins, 6–benzylaminopurine (6–BAP), was studied by two electrochemical methods, potentiometry and voltammetry. Attention was paid to the effect of ionic strength on their behaviour in water–methanol solutions. Potentiometric titrations enabled to determine the protonation constants (pKa) and voltammetric study (linear sweep voltammetry – LSV and elimination voltammetry with linear scan – EVLS) allowed to determine not only their reduction potentials but also deeper evaluation of their reduction processes. Due to potential antitumor activity of derivatives of 6–BAP it is very important to gain further insight into the mechanism of reduction depending on two parameters such as pH and ionic strength, which play a significant role in a living organism. Derivatives of adenine, known as cytokinins (CKs), are one of the five major groups of phytohormones, which support cell division, bud formation, branching of stems, and metabolism of plants. One of the most important cytokinins, 6–benzylaminopurine (6–BAP), was studied by two electrochemical methods, potentiometry and voltammetry. Attention was paid to the effect of ionic strength on their behaviour in water–methanol solutions. Potentiometric titrations enabled to determine the protonation constants (pKa) and voltammetric study (linear sweep voltammetry – LSV and elimination voltammetry with linear scan – EVLS) allowed to determine not only their reduction potentials but also deeper evaluation of their reduction processes. Due to potential antitumor activity of derivatives of 6–BAP it is very important to gain further insight into the mechanism of reduction depending on two parameters such as pH and ionic strength, which play a significant role in a living organism.
dcterms:title
Vliv iontové síly na protonační rovnováhu 6-benzylaminopurinu Vliv iontové síly na protonační rovnováhu 6-benzylaminopurinu
skos:prefLabel
Vliv iontové síly na protonační rovnováhu 6-benzylaminopurinu Vliv iontové síly na protonační rovnováhu 6-benzylaminopurinu
skos:notation
RIV/00216224:14310/11:00052417!RIV12-MSM-14310___
n17:predkladatel
n18:orjk%3A14310
n3:aktivita
n19:S n19:P n19:Z
n3:aktivity
P(LC06035), S, Z(MSM0021622412)
n3:dodaniDat
n5:2012
n3:domaciTvurceVysledku
n15:1956817 Serrano, Nuria n15:3790185 n15:6359922
n3:druhVysledku
n10:D
n3:duvernostUdaju
n22:S
n3:entitaPredkladatele
n8:predkladatel
n3:idSjednocenehoVysledku
238875
n3:idVysledku
RIV/00216224:14310/11:00052417
n3:jazykVysledku
n9:eng
n3:klicovaSlova
Cytokinins; phytohormones; 6–benzylaminopurine; Antitumor activity; Potentiometric titration; Cyclic voltammetry; protonation constants; Reduction potential; Electrode process
n3:klicoveSlovo
n14:Reduction%20potential n14:Antitumor%20activity n14:Potentiometric%20titration n14:Electrode%20process n14:Cytokinins n14:6%E2%80%93benzylaminopurine n14:phytohormones n14:protonation%20constants n14:Cyclic%20voltammetry
n3:kontrolniKodProRIV
[0C15DE47F21F]
n3:mistoKonaniAkce
Jetřichovice
n3:mistoVydani
Ústí nad Labem
n3:nazevZdroje
XXXI. Moderní Elektrochemické Metody
n3:obor
n7:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n23:LC06035
n3:rokUplatneniVysledku
n5:2011
n3:tvurceVysledku
Trnková, Libuše Pilařová, Iveta Balcarová, Zdeňka Serrano, Nuria
n3:typAkce
n4:WRD
n3:zahajeniAkce
2011-01-01+01:00
n3:zamer
n21:MSM0021622412
s:numberOfPages
5
n20:hasPublisher
BEST Servis
n16:isbn
978-80-254-9634-3
n11:organizacniJednotka
14310