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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F11%3A00052408%21RIV12-MSM-14310___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Benzylaminopurine (6–BAP),as the derivative of adenine,is involved among cytokinins (CKs).CKs are phytohormones which participate in regulation of growth and development processes of plants. Methoxy and chlorine derivatives of 6-BAP show antitumor activity (inhibitors of cyclin–dependent kinases) and due to this effect may be considered as potential cytostatics.The aim of this contribution is the determination of protonation constants of 6–BAP and its derivatives by potentiometric method for the different experimental conditions,such as methanol content (2.5-20 v/v percentages),temperature (5-37C) and ionic strength (I=0.1-1M NaCl).To determine the thermodynamic parameters deltaH and deltaS the temperature dependence of pKa was employed.The effect of the position of methoxy and chlorine group (X is Cl or OCH3) in 2',3'and 4'on benzene ring of 6–BAP was studied,too. Benzylaminopurine (6–BAP),as the derivative of adenine,is involved among cytokinins (CKs).CKs are phytohormones which participate in regulation of growth and development processes of plants. Methoxy and chlorine derivatives of 6-BAP show antitumor activity (inhibitors of cyclin–dependent kinases) and due to this effect may be considered as potential cytostatics.The aim of this contribution is the determination of protonation constants of 6–BAP and its derivatives by potentiometric method for the different experimental conditions,such as methanol content (2.5-20 v/v percentages),temperature (5-37C) and ionic strength (I=0.1-1M NaCl).To determine the thermodynamic parameters deltaH and deltaS the temperature dependence of pKa was employed.The effect of the position of methoxy and chlorine group (X is Cl or OCH3) in 2',3'and 4'on benzene ring of 6–BAP was studied,too.
dcterms:title
POTENTIOMETRIC AND VOLTAMMETRIC STUDY OF 6 – BENZYLAMINOPURINE AND ITS DERIVATIVES POTENTIOMETRIC AND VOLTAMMETRIC STUDY OF 6 – BENZYLAMINOPURINE AND ITS DERIVATIVES
skos:prefLabel
POTENTIOMETRIC AND VOLTAMMETRIC STUDY OF 6 – BENZYLAMINOPURINE AND ITS DERIVATIVES POTENTIOMETRIC AND VOLTAMMETRIC STUDY OF 6 – BENZYLAMINOPURINE AND ITS DERIVATIVES
skos:notation
RIV/00216224:14310/11:00052408!RIV12-MSM-14310___
n7:predkladatel
n13:orjk%3A14310
n3:aktivita
n10:S n10:P n10:Z
n3:aktivity
P(LC06035), S, Z(MSM0021622412)
n3:dodaniDat
n5:2012
n3:domaciTvurceVysledku
n6:3790185 n6:9007563 n6:1956817 n6:6359922
n3:druhVysledku
n8:O
n3:duvernostUdaju
n19:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
222057
n3:idVysledku
RIV/00216224:14310/11:00052408
n3:jazykVysledku
n14:eng
n3:klicovaSlova
6-BAP; cytokinins; potentiometry; cyclic voltammetry; elimination voltammetry
n3:klicoveSlovo
n4:6-BAP n4:cytokinins n4:cyclic%20voltammetry n4:elimination%20voltammetry n4:potentiometry
n3:kontrolniKodProRIV
[07D7028F969C]
n3:obor
n16:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n15:LC06035
n3:rokUplatneniVysledku
n5:2011
n3:tvurceVysledku
Pilařová, Iveta Balcarová, Zdeňka Lubal, Přemysl Trnková, Libuše
n3:zamer
n17:MSM0021622412
n18:organizacniJednotka
14310