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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F11%3A00049870%21RIV12-GA0-14310___
rdf:type
n14:Vysledek skos:Concept
dcterms:description
We have studied the chemistry of new 5-membered cyclic nitrones bearing different functional groups in positions 2 and 5 of the nitrone ring. Nitrones were treated with various dipolarophiles. Reactions offered isoxazoles as single diastereomers in all studied cases. The reaction scope and limitations of studied 1,3-DC are presented. Substituent effect of nitrones and effect of dipolarophile reactivity upon reaction conversions and reaction yields is discussed. We have studied the chemistry of new 5-membered cyclic nitrones bearing different functional groups in positions 2 and 5 of the nitrone ring. Nitrones were treated with various dipolarophiles. Reactions offered isoxazoles as single diastereomers in all studied cases. The reaction scope and limitations of studied 1,3-DC are presented. Substituent effect of nitrones and effect of dipolarophile reactivity upon reaction conversions and reaction yields is discussed.
dcterms:title
1,3-Dipolar cycloadditions of new functionalized cyclic nitrones 1,3-Dipolar cycloadditions of new functionalized cyclic nitrones
skos:prefLabel
1,3-Dipolar cycloadditions of new functionalized cyclic nitrones 1,3-Dipolar cycloadditions of new functionalized cyclic nitrones
skos:notation
RIV/00216224:14310/11:00049870!RIV12-GA0-14310___
n14:predkladatel
n16:orjk%3A14310
n3:aktivita
n6:P
n3:aktivity
P(GA203/09/1345)
n3:dodaniDat
n4:2012
n3:domaciTvurceVysledku
n11:5134056 n11:2333368 n11:8417377
n3:druhVysledku
n9:O
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
243929
n3:idVysledku
RIV/00216224:14310/11:00049870
n3:jazykVysledku
n18:eng
n3:klicovaSlova
Cyclic nitrone; Dipolar cycloaddition; Diastereoselectivity
n3:klicoveSlovo
n7:Cyclic%20nitrone n7:Diastereoselectivity n7:Dipolar%20cycloaddition
n3:kontrolniKodProRIV
[9A012CE35C92]
n3:obor
n12:CC
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n15:GA203%2F09%2F1345
n3:rokUplatneniVysledku
n4:2011
n3:tvurceVysledku
Buchlovič, Marian Hebanová, Simona Potáček, Milan
n10:organizacniJednotka
14310