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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F11%3A00049739%21RIV12-GA0-14310___
rdf:type
skos:Concept n7:Vysledek
dcterms:description
A set of CuIXL coordination polymers (X = Cl, Br, I; L = derivatives of pyrazine and bipyridine) with double-stranded staircase structures was analyzed by X-ray crystallography and luminescence spectroscopy to find a relationship between the structure and luminescence properties of the polymers. Our measurements have proved that luminescence emission wavelengths varied between 500–750 nm, after the polymers were irradiated by light with a wavelength of 370 nm. Although each coordination polymer has shown different emission maximum, we observed several interesting trends related to the structure of the compounds. There is a clear correlation between the emission maxima and the halide size and/or Cu–X distance, respectively. On the other hand, the substitution of the ligand L (pyrazine derivatives, 4,40-bipyridine) has no significant contribution to the emission spectra. A set of CuIXL coordination polymers (X = Cl, Br, I; L = derivatives of pyrazine and bipyridine) with double-stranded staircase structures was analyzed by X-ray crystallography and luminescence spectroscopy to find a relationship between the structure and luminescence properties of the polymers. Our measurements have proved that luminescence emission wavelengths varied between 500–750 nm, after the polymers were irradiated by light with a wavelength of 370 nm. Although each coordination polymer has shown different emission maximum, we observed several interesting trends related to the structure of the compounds. There is a clear correlation between the emission maxima and the halide size and/or Cu–X distance, respectively. On the other hand, the substitution of the ligand L (pyrazine derivatives, 4,40-bipyridine) has no significant contribution to the emission spectra.
dcterms:title
Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands
skos:prefLabel
Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands Luminescence properties of %22double-stranded staircase%22 copper(I) halide coordination polymers with N-containing ligands
skos:notation
RIV/00216224:14310/11:00049739!RIV12-GA0-14310___
n7:predkladatel
n8:orjk%3A14310
n4:aktivita
n18:P
n4:aktivity
P(GA203/08/1111), P(GP203/08/P325)
n4:cisloPeriodika
4
n4:dodaniDat
n11:2012
n4:domaciTvurceVysledku
n9:9206302 n9:1455990 n9:1424343
n4:druhVysledku
n19:J
n4:duvernostUdaju
n14:S
n4:entitaPredkladatele
n17:predkladatel
n4:idSjednocenehoVysledku
210084
n4:idVysledku
RIV/00216224:14310/11:00049739
n4:jazykVysledku
n5:eng
n4:klicovaSlova
coordination polymers copper luminescence
n4:klicoveSlovo
n16:coordination%20polymers%20copper%20luminescence
n4:kodStatuVydavatele
CZ - Česká republika
n4:kontrolniKodProRIV
[E044AAA8EF1C]
n4:nazevZdroje
New Journal of Chemistry
n4:obor
n12:CB
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
5
n4:projekt
n10:GA203%2F08%2F1111 n10:GP203%2F08%2FP325
n4:rokUplatneniVysledku
n11:2011
n4:svazekPeriodika
35
n4:tvurceVysledku
Nather, Christian Pospíšil, Jiří Jess, Inke Nečas, Marek Táborský, Petr
s:issn
1144-0546
s:numberOfPages
4
n15:organizacniJednotka
14310