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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F10%3A00046765%21RIV11-GA0-14310___
rdf:type
skos:Concept n15:Vysledek
dcterms:description
Nitrogen post-discharge kinetics has been investigated many years. The sensitivity to admixtures has been proven in previous studies and this fact leads us to use this kind of discharge for experiments simulating elemental analysis. A lower pressure and temperature are factors which, among others, discriminate its analytical application. Sample introduction systems for solid, liquid and gas samples were tested: a simple flow-through evaporator for mercury, an electrothermic vaporizer for some solid metals and two systems for hydride generation. The vaporizers for mercury or liquid metals are based on saturation of the carrier gas with the sample vapours, whereas the hydride forming elements react in their acidic matrices with sodium tetrahydridoborate. The created mixture of the carrier gas with the metal vapour or hydride is taken into the discharge space. Vibrational population changes of upper electronic nitrogen states were analyzed and some responsible kinetic reactions were proposed. Nitrogen post-discharge kinetics has been investigated many years. The sensitivity to admixtures has been proven in previous studies and this fact leads us to use this kind of discharge for experiments simulating elemental analysis. A lower pressure and temperature are factors which, among others, discriminate its analytical application. Sample introduction systems for solid, liquid and gas samples were tested: a simple flow-through evaporator for mercury, an electrothermic vaporizer for some solid metals and two systems for hydride generation. The vaporizers for mercury or liquid metals are based on saturation of the carrier gas with the sample vapours, whereas the hydride forming elements react in their acidic matrices with sodium tetrahydridoborate. The created mixture of the carrier gas with the metal vapour or hydride is taken into the discharge space. Vibrational population changes of upper electronic nitrogen states were analyzed and some responsible kinetic reactions were proposed.
dcterms:title
Sample introduction into a flowing nitrogen post discharge and kinetics studies Sample introduction into a flowing nitrogen post discharge and kinetics studies
skos:prefLabel
Sample introduction into a flowing nitrogen post discharge and kinetics studies Sample introduction into a flowing nitrogen post discharge and kinetics studies
skos:notation
RIV/00216224:14310/10:00046765!RIV11-GA0-14310___
n3:aktivita
n14:Z n14:S n14:P
n3:aktivity
P(GA202/08/1106), S, Z(MSM0021622411)
n3:dodaniDat
n9:2011
n3:domaciTvurceVysledku
n10:4250583 n10:2888165 n10:1224670 n10:9001840 n10:2647788
n3:druhVysledku
n16:O
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
286323
n3:idVysledku
RIV/00216224:14310/10:00046765
n3:jazykVysledku
n4:eng
n3:klicovaSlova
glow discharge; post discharge; nitrogen; afterglow; flowing; hydride; mercury; metal.
n3:klicoveSlovo
n6:mercury n6:hydride n6:post%20discharge n6:flowing n6:glow%20discharge n6:nitrogen n6:metal. n6:afterglow
n3:kontrolniKodProRIV
[35C51DFD803F]
n3:obor
n17:CA
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
7
n3:projekt
n12:GA202%2F08%2F1106
n3:rokUplatneniVysledku
n9:2010
n3:tvurceVysledku
Hrdlička, Aleš Kanický, Viktor Mazánková, Věra Otruba, Vítězslav Bocková, Ivana Krčma, František Procházková, Markéta
n3:zamer
n11:MSM0021622411
n8:organizacniJednotka
14310