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Statements

Subject Item
n2:RIV%2F00216224%3A14310%2F10%3A00046191%21RIV11-MSM-14310___
rdf:type
n17:Vysledek skos:Concept
dcterms:description
H3do3a is heptadentate macrocyclic ligand capable of formation of the thermodynamic stable complex with europium(III) ion and it is able to form ternary lanthanide species with mono- and bidentate ligands. This contribution enlarges the study of the formation of ternary complex europium(III) species with important bioanalytes (carbonate, citrate, hydrogencarbonate, oxalate) or other ligands (5-sulfosalicylic, phthalic and picolinic acids) at pH = 7.2 by means of molecular luminescence spectroscopy. The formation of ternary complex species is accompanied by the increase of luminescence. The phenomenon is the consequence of exclusion of water molecules from the first coordination sphere substitution as the most effective quenchers. The simultaneous increase of coordination number of europium(III) ion from seven to nine. Picolinate form ternary complex species demonstrating high fluorescence intensity and the application of achieved results for determination of the bioanalytes is discussed. H3do3a is heptadentate macrocyclic ligand capable of formation of the thermodynamic stable complex with europium(III) ion and it is able to form ternary lanthanide species with mono- and bidentate ligands. This contribution enlarges the study of the formation of ternary complex europium(III) species with important bioanalytes (carbonate, citrate, hydrogencarbonate, oxalate) or other ligands (5-sulfosalicylic, phthalic and picolinic acids) at pH = 7.2 by means of molecular luminescence spectroscopy. The formation of ternary complex species is accompanied by the increase of luminescence. The phenomenon is the consequence of exclusion of water molecules from the first coordination sphere substitution as the most effective quenchers. The simultaneous increase of coordination number of europium(III) ion from seven to nine. Picolinate form ternary complex species demonstrating high fluorescence intensity and the application of achieved results for determination of the bioanalytes is discussed.
dcterms:title
Carbonate sensor based on macrocyclic DO3A ligand Carbonate sensor based on macrocyclic DO3A ligand
skos:prefLabel
Carbonate sensor based on macrocyclic DO3A ligand Carbonate sensor based on macrocyclic DO3A ligand
skos:notation
RIV/00216224:14310/10:00046191!RIV11-MSM-14310___
n3:aktivita
n4:P n4:V n4:S
n3:aktivity
P(LC06035), P(ME09065), P(OC 179), S, V
n3:dodaniDat
n5:2011
n3:domaciTvurceVysledku
n11:5135001 n11:9007563
n3:druhVysledku
n21:D
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
249617
n3:idVysledku
RIV/00216224:14310/10:00046191
n3:jazykVysledku
n20:eng
n3:klicovaSlova
Macrocyclic ligand; Ln(III) ions; ternary complex; anion sensor
n3:klicoveSlovo
n8:ternary%20complex n8:anion%20sensor n8:Macrocyclic%20ligand n8:Ln%28III%29%20ions
n3:kontrolniKodProRIV
[F5D01DAB13D0]
n3:mistoKonaniAkce
Praha
n3:mistoVydani
Praha
n3:nazevZdroje
Abstract book of XIV. International Symposium on Luminescence Spectrometry
n3:obor
n19:CB
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n7:ME09065 n7:LC06035 n7:OC%20179
n3:rokUplatneniVysledku
n5:2010
n3:tvurceVysledku
Lubal, Přemysl Vaněk, Jakub
n3:typAkce
n12:WRD
n3:zahajeniAkce
2010-07-13+02:00
s:numberOfPages
216
n16:hasPublisher
Faculty of Pharmacy, Charles University, Prague
n6:isbn
978-80-254-6830-2
n18:organizacniJednotka
14310